Plant protection agents based on pyrazolecarboxylic acid derivatives

ABSTRACT

The present invention relates to agents for protecting crop plants from the phytotoxic side effects of herbicides, which agents contain a compound of the formula ##STR1## wherein Y denotes C--H or N, 
     the symbols R 1  independently of one another denote alkyl, halo-alkyl, alkoxy, haloalkoxy or halogen, 
     R 2  denotes alkyl or cycloalkyl, 
     X denotes COOR 3 , CON(R 4 ) 2 , COSR 3 , CN or ##STR2## R 3  denotes an alkali metal or alkaline earth metal, hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, or phenylalkyl, it being possible for phenyl to be substituted by halogen, or trisalkylsilylalkyl or alkoxyalkyl, 
     the symbols R 4  independently of one another denote H, alkyl or cycloalkyl, which can be substituted, or radicals R 4  together with the N atom linking them form a 4- to 7-membered heterocyclic ring and 
     n denotes 1 to 3, 
     in combination with a herbicide.

This application is a continuation of application Ser. No. 07/324,300, filed Mar. 15, 1989, now abandoned.

DESCRIPTION

The present invention relates to agents for protecting crop plants from the phytotoxic side effects of herbicides, which agents contain a compound of the formula I ##STR3## wherein Y denotes C--H or N,

the symbols R₁ independently of one another denote (C₁ -C₄)-alkyl, (C₁ -C₄)-haloalkyl, (C₁ -C₄)alkoxy, (C₁ -C₄)-haloalkoxy or halogen,

R2 denotes (C₁ -C₁₂)-alkyl or (C₃ -C₇)-cycloalkyl,

X denotes COOR₃, CON(R₄)₂, COSR₃, CN or ##STR4## R₃ denotes an alkali metal or alkaline earth metal, hydrogen, (C₁ -C₁₀)-alkyl, (C₃ -C₂₀)-alkenyl, (C₃ -C 10)-alkynyl, (C₃ -C₇)-cycloalkyl or phenyl-(C₁ -C 4)-alkyl, it being possible for phenyl to be substituted by halogen, or tris-(C₁ -C₄)-alkyl-silyl (C₁ -C 4)-alkyl or (C₁ -C₄)-alkoxy-(C₁ -C₄)-alkyl,

the symbols R₄ independently of one another denote H, (C₁ -C₁₀)-alkyl or (C₃ -C₇)-cycloalkyl, which can be substituted, or 2 radicals R₄ together with the N atom linking them form a 4- to 7-membered heterocyclic ring and

n denotes 1 to 3,

in combination with a herbicide.

In this formula, alkyl denotes straight-chain or branched alkyl.

In the case where ##STR5## two identical radicals of a compound of the formula I are linked to one another.

Halogen preferably denotes chlorine or bromine, alkali metal preferably denotes Li, Na or K and alkaline earth metal denotes in particular Ca. The heterocyclic ring formed from the two radicals R₄ together with the N atom is preferably pyrrolidine, morpholine, 1,2,4-triazole or piperidine.

The compounds of the formula I in which Y denotes CH, R₁ denotes halogen or (C₁ -C₄)-haloalkyl, R₂ denotes (C₁ -C₆)-alkyl, X denotes COOR₃, R₃ denotes H or (C₁ -C₆)-alkyl and n denotes 1 or 2 are furthermore preferred.

The compounds of the formula I in which Y denotes CH, R₁ denotes Cl, Br or CF₃, R₂ denotes (C₁ -C₄)-alkyl, X denotes COOR₃, R₃ denotes (C₁ -C₄)-alkyl and n denotes 2 are particularly preferred.

The compounds of the formula I in which Y denotes CH, R₁ denotes 2,4-Cl₂, R₂ denotes isopropyl, X denotes COOR₃ and R₃ denotes (C₁ -C₁₀)-alkyl are novel and the present invention likewise relates to them. In these compounds, the 5-position is preferred for R₂ and the 3-position is preferred for X. The compound in which Y denotes CH, R_(I) denotes 2,4-Cl₂, R₂ denotes 5-isopropyl and X denotes 3-COOC₂ H₅ is of particular importance.

The compounds of-the formula I can be prepared by methods which are known from the literature (HU-PS 153,762 or Chem. Abstr. 68, 87293 y (1968)). For further derivatization, the radical --COOR₃ is converted into other radicals mentioned for X in a known manner, for example by hydrolysis, transesterification, amidation, salt formation and the like, as is described, for example, in DE-OS 3,444,918 or 3,442,690.

When plant treatment agents, in particular herbicides, are used, undesirable damage which cannot be tolerated may occur to crop plants. On application of herbicides after emergence of the crop plants, in particular, there is therefore often the need to avoid the risk of possible phytotoxicity.

Various compounds have already been described for this use (for example EP-A 152,006).

Surprisingly, it has been found that compounds of the formula I have the property of preventing or completely eliminating phytotoxic side effects of plant protection agents, in particular herbicides, when used in crops of useful plants. The compounds of the formula I are capable of completely eliminating the harmful side effects of herbicides without curtailing the activity of these herbicides against harmful plants.

Such compounds which have the property of protecting crop plants from phytotoxic damage by herbicides without impairing the actual herbicidal action of these agents are called "antidotes" or "safeners".

The field of use of conventional herbicides can be widened quite considerably by addition of the safener compound of the formula I.

The present invention thus also relates to a method of protecting crop plants from the phytotoxic side effects of plant protection agents, in particular herbicides, which comprises treating the plants, plant seeds or cultivation areas with a compound of the formula I before, after or at the same time as the plant protection agent.

Herbicides of which the phytotoxic side effects can be reduced by means of the compounds of the formula I are, for example, carbamates, thiocarbamates, halogenoacetanilides, substituted phenoxy-, naphthoxy- and phenoxy-phenoxy-carboxylic acid derivatives and heteroaryloxyphenoxycarboxylic acid derivatives, such as quinolyloxy-, quinoxalyloxy-, pyridyloxy-, benzoxazolyloxy- and benzothiazolyloxy-phenoxy-carboxylic acid esters, and furthermore dimedoneoxime derivatives. Of these, phenoxy-phenoxy- and heteroaryloxyphenoxy-carboxylic acid esters are preferred. Possible esters here are, in particular, lower alkyl, alkenyl and alkynyl esters.

The following herbicides may be mentioned as examples, without a limitation being intended by these:

A) Herbicides of the (C₁ -C₄)-alkyl, (C₂ -C₄)-alkenyl or (C₃ -C₄)-alkynyl phenoxyphenoxy- and heteroaryloxyphenoxycarboxylate type, such as

methyl 2-(4-(2,4-dichlorophenoxy)-phenoxy)-propionate,

methyl 2-(4-(4-bromo-2-chlorophenoxy)-phenoxy)propionate,

methyl 2-(4-(4-trifluoromethylphenoxy)-phenoxy)propionate,

methyl 2-(4-(2-chloro-4-trifluoromethylphenoxy)-phenoxy)-propionate,

methyl 2-(4-(2,4-dichlorobenzyl)-phenoxy)-propionate, 2-isopropylideneamino-oxyethyl

(R)-2-[4-(6-chloro-quinoxalin-2-yloxy)-phenoxy]-propionate (propaquizafop),

ethyl 4-(4-(4-trifluoromethylphenoxy)-phenoxy)-pent-2-enoate,

ethyl 2-(4-(3,5-dichloropyridyl-2-oxy)-phenoxy)propionate,

propargyl 2-(4-(3,5-dichloropyridyl-2-oxy)-phenoxy)-propionate,

ethyl 2-(4-(6-chlorobenzoxazol-2-yl-oxy)-phenoxy)propionate,

ethyl 2-(4-(6-chlorobenzothiazol-2-yl-oxy)-phenoxy)propionate,

methyl 2-(4-(3-chloro-5-trifluoromethyl-2-pyridyloxy)-phenoxy)-propionate,

butyl 2-(4-(5-trifluoromethyl-2-pyridyloxy)-phenoxy)propionate,

ethyl 2-(4-(6-chloro-2-quinoxalyloxy)-phenoxy)propionate,

ethyl 2-(4-(6-fluoro-2-quinoxalyloxy)-phenoxy)propionate,

propargyl 2-(4-(5-chloro-3-fluoro-pyridyl-2-oxy)-phenoxy)-propionate,

ethyl 2-(4-(6-chloro-2-quinolyloxy)-phenoxy)-propionate,

trimethylsilylmethyl 2-(4-(3,5-dichloropyridyl-2-oxy)-phenoxy)-propionate,

ethyl 2-(4-(3-chloro-5-trifluoromethoxy-2-pyridyloxy)-phenoxy)-propionate,

B) Chloroacetanilide herbicides, such as

N-methoxymethyl-2,6-diethyl-chloroacetanilide,

N-(3'-methoxyprop-2'-yl)-methyl-6-ethyl-chloroacetanilide and

N-(3-methyl-1,2,4-oxdiazol-5-yl-methyl)-chloroacetic acid 2,6-dimethylanilide,

C) Thiocarbamates, such as

S-ethyl N,N-dipropylthiocarbamate or

S-ethyl N,N-diisobutylthiocarbamate

D) Dimedone derivatives, such as

2-(N-ethoxybutyrimidoy L)-5-(2-ethylthiopropyl)-3-hydroxy-2-cyclohexen-1-one,

2-(N-ethoxybutyrimidoy 1)-5-(2-phenylthiopropyl)-3-hydroxy-2-cyclohexen-1-one,

2-(1-allyloxyiminobuty 1)-4-methoxycarbonyl-5,5-di-methyl-3-oxocyclohexenol,

2-(N-ethoxypropionamidoyl)-5-mesityl-3-hydroxy-2-cyclohexen-1-one,

2-(N-ethoxybutyrimidoyl)-3-hydroxy-5-(thian-3-yl)-2-cyclohexen-1-one,

2-[1-(ethoxyimino)-butyl]-3-hydroxy-5-(2H-tetrahydrothiopyran-3-yl)-2-cyclohexen-1-one (BASF 517),

2-[1-(ethoxyimino)-propyl]-3-hydroxy-5-mesitylcyclohex-2-enone (PP 604 from ICI) and

(+)-2-[(E)-3-chloroallyloxyiminopropyl]-5-(2-ethylthiopropyl)-3-hydroxycyclohex-2-enone (clethodim).

Of the herbicides which can be combined according to the invention with the compounds of the formula I, the compounds listed under A) may be mentioned as preferred, in particular ethyl 2-(4-(6-chlorobenzoxazol-2-yl-oxy)-phenoxy)-propionate, ethyl 2-(4-(6-chlorobenzothiazol-2-yl-oxy)-phenoxy)-propionate and propargyl 2-(4-(5-chloro-3-fluoropyridyl-2-oxy)-phenoxy)-propionate. Of the substances mentioned under D), 2-(N-ethoxypropionamidoyl)5-mesityl-3-hydroxy-2-cyclohexen-1-one is of particular importance.

The ratio of the amounts of safener (compound I): herbicide can vary within wide limits of between 1:10 and 10:1, in particular between 2:1 and 1:10.

The particular optimum amounts of herbicide and safener depend on the type of herbicide used or on the type of safener used and on the nature of the plant crop to be treated, and can be determined from case to case by appropriate experiments.

The main fields of use for application of the safeners are, above all, cereal crops (wheat, rye, barley and oats), rice, maize and sorghum, and also cotton, sugarbeet, cane sugar and soya bean.

Depending on their properties, the safeners can be used for pretreatment of the seeds of the crop plants (dressing of the seeds) or can be introduced into the seed furrows before sowing or used together with the herbicide before or after emergence of the plants. Preemergence treatment includes both treatment of the cultivation area before sowing and treatment of the sown cultivation areas on which there is as yet no growth.

However, simultaneous use of the antidote with the herbicide in the form of tank mixes or finished formulations is preferred.

The compounds of the formula I or the combination thereof with one or more of the herbicides or herbicide groups mentioned can be formulated in various ways as determined by the biological and/or chemical-physical parameters. Suitable formulation possibilities are therefore: wettable powders (WP), emulsifiable concentrates (EC), aqueous solutions (SC), emulsions, sprayable solutions, oil- or water-based dispersions (SC), suspoemulsions (SC), dusting agents (DP), dressing agents, granules in the form of micro, spray, coated and adsorption granules, water-dispersible granules (WG), ULV formulations, microcapsules or waxes.

These individual types of formulation are known in principle and are described, for example, in: Winnacker-Kuchler, "Chemische Technologie (Chemical Technology)", Volume 7, C. Hauser Verlag Munchen, 4th edition 1986; van Falkenberg, "Pesticides Formulations", Marcel Dekker N.Y., 2nd edition, 1972-73; and K. Martens, "Spray Drying Handbook", 3rd edition 1979, G. Goodwin Ltd. London.

The formulation auxiliaries needed, such as inert materials, surfactants, solvents and other additives, are likewise known and are described, for example, in: Watkins, "Handbook of Insecticide Dust Diluents and Carriers" 2 nd edition, Darland Books, Caldwell N.J,; H. v. Olphen, "Introduction to Clay Colloid Chemistry", 2nd edition, Wiley & Sons, N.Y.; Marschen, "Solvents Guide", 2nd edition, Interscience, N.Y. 1950; McCutcheon's, "Detergents and Emulsifiers Annual", MC Publ. Corp., Ridgewood N.J.; Sisley and Wood, "Encyclopedia of Surface Active A gents , Chem. Publ. Co. Inc., N.Y. 1964; Schonfeldt, "Grenzflachenaktive Athylenoxidaddukte (Surface-active ethylene oxide adducts)", Wiss. Verlagsgesell., Stuttgart 1976; and Winnacker-Kuchler, "Chemische Technologie (Chemical Technology)", Volume 7, C. Hauser Verlag Munchen, 4th edition 1986.

On the basis of these formulations, it is also possible to prepare combinations with other pesticidally active substances, fertilizers and/or growth regulators, for example in the form of a finished formulation or as a tank mix. Wettable powders are preparations which are uniformly dispersible in water and, in addition to the active compound a nd apart from a diluent or inert substance, also contain wetting agents, for example polyoxyethylated alkylphenols, polyoxyethylated fatty alcohols and alkyl- or alkylphenol-sulfonates, and dispersing agents, for example sodium lignin-sulfonate, sodium 2,2'-dinaphthylmethane-6,6'-disulfonate, sodium dibutyl-naphthalene-sulfonate or sodium oleyl-methyl-taurate. Emulsifiable concentrates are prepared by dissolving the active compound in an organic solvent, for example butanol, cyclohexanone, dimethylformamide, xylene or higher-boiling aromatics or hydrocarbons, with the addition of one or more emulsifiers. Examples of emulsifiers which can be used are: calcium alkylarylsulfonates, such as Ca dodecylbenzenesulfonate, or nonionic emulsifiers, such as fatty acid polyglycol esters, alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide/ethylene oxide condensation products, alkyl polyethers, sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters or polyoxyethylene sorbitol esters. Dusts are obtained by grinding the active compound with finely divided solid substances, for example talc or naturally occurring clays, such as kaolin, bentonite, pyrophyllite or diatomaceous earth. Granules can be prepared either by spraying the active compound onto an adsorbent granular inert material or by applying active compound concentrates to the surface of carrier substances, such as sand, kaolinires or a granular inert material, by means of adhesives, for example polyvinyl alcohol, sodium polyacrylate or mineral oils. Suitable active compounds can also be granulated in the manner customary for the preparation of fertilizer granules if desired as a mixture with fertilizers.

The active compound concentration in wettable powders is, for example, about 10 to 90% by weight, the remainder to make up to 100% by weight consisting of customary formulation constituents. The active compound concentration in emulsifiable concentrates can be about 5 to 80% by weight. Dust-like formulations usually contain 5 to 20% by weight of active compound, and sprayable solutions contain about 2 to 20% by weight. In granules, the active compound content partly depends on whether the active compound is in the liquid or solid form and on what granulation auxiliaries, fillers and the like are used.

The active compound formulations mentioned additionally contain, if appropriate, the particular customary tackifiers, wetting agents, dispersing agents, emulsifiers, penetration agents, solvents, fillers or carrier substances.

For use, the concentrates in the commercially available form are diluted in the customary manner if appropriate, for example by means of water in the case of wettable powders, emulsifiable concentrates, dispersions and in some cases also microgranules. Dust-like and granular formulations and sprayable solutions are usually not further diluted with more inert substances before use.

The application amount required for the compounds of the formula I varies according o the external conditions, such as temperature, humidity, nature of the herbicide used and others. It can vary within wide limits, for example between 0.005 and 10.0 kg/ha or more of active substance, but is preferably between 0.01 and 5 kg/ha.

The following examples serve to illustrate the invention:

A. Formulation Examples

a) A dusting agent is obtained by mixing 10 parts by weight of a compound of the formula I and 90 parts by weight of talc or an inert substance and comminuting the mixture in an impact mill.

b) A wettable powder which is readily dispersible in water is obtained by mixing 25 parts by weight of a compound of the formula I, 64 parts by weight of kaolin-containing quartz, as an inert substance, 10 parts by weight of potassium lignin-sulfonate and 1 part by weight of sodium oleoyl-methyl-taurate, as the wetting and dispersing agents, and grinding the mixture in a pinned disk mill.

c) A dispersion concentrate which is readily dispersible in water is obtained by mixing 20 parts by weight of a compound of the formula I with 6 parts by weight of alkylphenol polyglycol ether ((R)Triton X 207), 3 parts by weight of isotridecanol polyglycol ether (8 mol of ethylene oxide) and 71 parts by weight of paraffinic mineral oil (boiling range, for example, about 255 to more than 277° C.) and grinding the mixture to a fineness of less than 5 microns in a bead mill.

d) An emulsifiable concentrate is obtained from 15 parts by weight of a compound of the formula I, 75 parts by weight of cyclohexanone, as the solvent, and 10 parts by weight of oxyethylated nonylphenol, as the emulsifier.

e) A concentrate which is readily emulsifiable in water and consists of a phenoxycarboxylic acid ester and an antidote (10:1) is obtained from:

2.00% by weight of ethyl 2-(4-(6-chlorobenzoxazol-2yl-oxy)-phenoxy)-propionate

1.20% by weight of a compound of the formula I

69.00% by weight of xylene

7.80% by weight of calcium dodecylbenzenesulfonate

6.00% by weight of ethoxylated nonylphenol (10 mol of ethylene oxide) and

4.00% by weight of ethoxylated castor oil (40 mol of ethylene oxide)

The formulation is carried out as described under Example a),

f) A concentrate which is readily emulsifiable in water and consists of a phenoxycarboxylic acid ester and an antidote (1:10) is obtained from:

4.0% by weight of ethyl 2-(4-(6-chlorobenzoxazol-2yl-oxy)-phenoxy)-propionate

40.0% by weight of a compound of the formula I

30.0% by weight of xylene

20.0% by weight of cyclohexanone

4.0% by weight of calcium dodecylbenzenesulfonate and

2.0% by weight of ethoxylated castor oil (40 mol of ethylene oxide)

B. Chemical Examples

1. Ethyl 1-(4-chlorophenyl)-5(3)-methyl-pyrazole-3(5)-carboxylate

4.3 g of 4-chlorophenylhydrazine II and 0.1 g of p-toluenesulfonic acid are added to 15.8 g of ethyl acetylpyruvate I in 100 ml of toluene with stirring and the mixtures heated, using a water separator. When no further water passes over, the mixture is allowed to cool and is diluted with 100 ml of toluene and washed with 100 ml of 3 N hydrochloric acid, 00 ml of water, 100 ml of saturated NaHCO₃ solution and 100 ml of water, and the organic phase is concentrated to dryness and chromatographed over silica gel (mobile phase petroleum ether >ethyl acetate).

Example No.

1 Ethyl 1-(4-chlorophenyl)-5-methyl-pyrazole-3-carboxylate (melting point 121°-124° C.)

62 Ethyl 1-(4-chlorophenyl)-3-methyl-pyrazole-5-carboxylate (oil)

Pyrazoles with a different substitution pattern in the aromatic part and/or a different allyl radical are prepared analogously and if appropriate derivatized on the carbonyl function. The derivatives are summarized in Table I.

                                      TABLE I                                      __________________________________________________________________________     Alkyl-aryl-pyrazolecarboxylic acid derivatives                                  ##STR6##                                             (I)                      Y = CH                                                                                                                         Melting point/                 Example                                         boiling point                  No.  (R.sub.1).sub.n                                                                            R.sub.2   X                    mm Hg [°C.]             __________________________________________________________________________      2   4-Cl        5-CH.sub.3                                                                               3-COOCH.sub.3                                        3   "           "         3-COO-n-C.sub.3 H.sub.7                              4   "           "         3-COO-i-C.sub.3 H.sub.7                              5   "           "         3-COO-n-C.sub.4 H.sub.9                              6   "           "         3-COO-n-C.sub.5 H.sub.11                             7   "           "         3-COO-n-C.sub.6 H.sub.13                             8   "           "         3-COO-n-C.sub.8 H.sub.17                             9   "           "         3-COO-n-C.sub.10 H.sub.21                            10  "           "                                                                                         ##STR7##                                            11  "           "         3-COOH               157-160                         12  "           "         3-COOLi                                              13  "           "         3-COONa                                              14  "           "         3-COOK                                               15  "           "         3-COOCa.sub.1 /.sub.2                                16  "           "         3-COO-c-C.sub.4 H.sub.7                              17  "           "         3-COO-c-C.sub.6 H.sub.13                             18  "           "         3-COOCH.sub.2C.sub.6 H.sub.5                         19  "           "         3-COCCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)        20  "           "         3-COOCH.sub.2 CHCH.sub.2                             21  "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                      22  "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  23  "           "         3-COOCH.sub.2 CCH                                    24  "           "         3-COOC.sub.2 H.sub.4CCH                              25  "           "         3-COO-n-C.sub.5 H.sub.10 CCH                         26  "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                     27  "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                       28  "           "         3-CONH.sub.2                                         29  "           "         3-CN                                                 30  "           "         3-CONHCH.sub.3                                       31  4-Cl        5-CH.sub.5                                                                               3-CONHC.sub.2 H.sub.5                                32  "           "         3-CONH-n-C.sub.3 H.sub.7                             33  "           "         3-CONH-n-C.sub.4 H.sub.9                             34  "           "         3-CONH-n-C.sub.6 H.sub.13                            35  "           "         3-CONH-n-C.sub.10 H.sub.21                           36  "           "         3-CONH-i-C.sub.3 H.sub.7                             37  "           "         3-CON(CH.sub.3).sub.2                                38  "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   39  "           "         3-CON(C.sub.2 H.sub.5).sub.2                         40  "           "                                                                                         ##STR8##                                            41  "           "                                                                                         ##STR9##                                            42  "           "                                                                                         ##STR10##                                           43  "           "                                                                                         ##STR11##                                           44  "           "         3-CONH-c-C.sub.6 H.sub.11                            45  "           "         3-CONH-c-C.sub.3 H.sub.5                             46  "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                   47  "           "         3-COSH                                               48  "           "         3-COSNa                                              49  "           "         3-COSCH.sub.3                                        50  "           "         3-COSC.sub.2 H.sub.5                                 51  "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                        52  "           "         3-COS-nC.sub.8 H.sub.17                              53  "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                       54  "           "         3-COSCH.sub.2 CHCH.sub.2                             55  "           "         3-COSCH.sub.2 CCH                                    56  "           "         3-COS-c-C.sub.6 H.sub.11                             57  "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                     58  "           "         3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           59  "           "                                                                                         ##STR12##                                           60  "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub. 2             61  4-Cl        3-CH.sub.3                                                                               5-COOCH.sub.3                                        63  "           "         5-COOnC.sub.3 H.sub.7                                64  "           "         5-COO-i-C.sub.3 H.sub.7                              65  "           "         5-COO-n-C.sub.4 H.sub.9                              66  "           "         5-COO-n-C.sub.5 H.sub.11                             67  "           "         5-COO-n-C.sub.6 H.sub.13                             68  "           "         5-COO-n-C.sub.8 H.sub.17                             69  "           "         5-COO-n-C.sub.10 H.sub.21                            70  "           "                                                                                         ##STR13##                                           71  "           "         5-COOH                                               72  "           "         5-COOLi                                              73  "           "         5-COONa                                              74  "           "         5-COOK                                               75  "           "         5-COOCa.sub.1 /.sub.2                                76  "           "         5-COO-c-C.sub.4 H.sub.7                              77  "           "         5-COO-c-C.sub.6 H.sub.11                             78  "           "         5-COOCH.sub.2 C.sub. 6 H.sub.5                       79  "           "         5-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)        80  "           "         5-COOCH.sub.2 CHCH.sub.2                             81  "           "         5-COOC.sub.2 H.sub.4 CHCH.sub.2                      82  "           "         5-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  83  "           "         5-COOCH.sub.2 CCH                                    84  "           "         5-COOC.sub.2 H.sub.4 CCH                             85  "           "         5-COO-n-C.sub.5 H.sub.10 CCH                         86  "           "         5-COOCH.sub.2 Si(CH.sub.3).sub.3                     87  "           "         5-COOC.sub.2 H.sub.4 OCH.sub.3                       88  "           "         5-CONH.sub.2                                         89  "           "         5-CN                                                 90  "           "         5-CONHCH.sub.3                                       91  4-Cl        3-CH.sub.3                                                                               5-CONHC.sub.2 H.sub.5                                92  "           "         5-CONH-n-C.sub.3 H.sub.7                             93  "           "         5-CONH-n-C.sub.4 H.sub.9                             94  "           "         5-CONH-n-C.sub.6 H.sub.13                            95  "           "         5-CONH-n-C.sub.10 H.sub.21                           96  "           "         5-CONH-i-C.sub.3 H.sub.7                             97  "           "         5-CON(CH.sub. 3).sub.2                               98  "           "         5-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   99  "           "         5-CON(C.sub.2 H.sub.5).sub.2                        100  "           "                                                                                         ##STR14##                                          101  "           "                                                                                         ##STR15##                                          102  "           "                                                                                         ##STR16##                                          103  "           "                                                                                         ##STR17##                                          104  "           "         5-CONH-c-C.sub.6 H.sub.11                           105  "           "         5-CONH-c-C.sub.3 H.sub.5                            106  "           "         5-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  107  "           "         5-COSH                                              108  "           "         5-COSNa                                             109  "           "         5-COSCH.sub.3                                       110  "           "         5-COSC.sub.2 H.sub.5                                111  "           "         5-COSCH.sub.2 C.sub.6 H.sub.5                       112  "           "         5-COS-nC.sub.8 H.sub.17                             113  "           "         5-COSC.sub.2 H.sub.4 OCH.sub.3                      114  "           "         5-COSCH.sub. 2 CHCH.sub.2                           115  "           "         5-COSCH.sub.2 CCH                                   116  "           "         5-COS-c-C.sub.6 H.sub.11                            117  "           "         5-COSCH.sub.2 Si(CH.sub.3).sub.3                    118  "           "         5-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          119  "           "                                                                                         ##STR18##                                          120  "           "         5-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             121  2,4-Cl.sub.2                                                                               5-CH.sub.3                                                                               3-COOCH.sub.3        87-93                          122  "           "         3-COOC.sub.2 H.sub.5 78-81                          123  "           "         3-COO-n-C.sub.3 H.sub.7                                                                             99-100                         124  "           "         3-COO-i-C.sub.3 H.sub.7                                                                             65-70                          125  "           "         3-COO-n-C.sub.4 H.sub.9                                                                             76-78                          126  "           "         3-COO-n-C.sub.5 H.sub.11                            127  "           "         3-COO-n-C.sub.6 H.sub.13                                                                            Oil                            128  "           "         3-COO-n-C.sub.8 H.sub.17                                                                            47-49                          129  "           "         3-COO-n-C.sub.10 H.sub.21                           130  "           "                                                                                         ##STR19##           114-117                        131  "           "         3-COOH               112-115                        132  "           "         3-COOLi              >250                           133  "           "         3-COONa              >250                           134  "           "         3-COOK                                              135  "           "         3-COOCa.sub.1 /.sub.2                                                                               187-188                        136  "           "         3-COO-c-C.sub.4 H.sub.7                             137  "           "         3-COO-c-C.sub.6 H.sub.11                                                                            72-74                          138  "           "         3-COOCH.sub.2 C.sub.6 H.sub.5                                                                       Oil                            139  "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       140  "           "         3-COOCH.sub.2 CHCH.sub.2                                                                            Oil                            141  "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     142  "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 143  "           "         3-COOCH.sub.2 CCH    101-102                        144  "           "         3-COOC.sub.2 H.sub.4 CCH                            145  "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        146  "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                                                                    67-70                          147  "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                                                                      Oil                            148  "           "         3-CONH.sub.2         181                            149  "           "         3-CN                                                150  "           "         3-CONHCH.sub.3       161-162                        151  2,4-Cl.sub.2                                                                               5-CH.sub.3                                                                               3-CONHC.sub.2 H.sub.5                                                                               87-90                          152  "           "         3-CONH-n-C.sub.3 H.sub.7                                                                            89-92                          153  "           "         3-CONH-n-C.sub.4 H.sub.9                                                                            55-60                          154  "           "         3-CONH-n-C.sub.6 H.sub.13                                                                           68-71                          155  "           "         3-CONH-n-C.sub.10 H.sub.21                          156  "           "         3-CONH-i-C.sub.3 H.sub.7                            157  "           "         3-CON(CH.sub.3).sub.2                                                                               99-103                         158  "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  159  "           "         3-CON(C.sub.2 H.sub.5).sub.2                                                                        Oil                            160  "           "                                                                                         ##STR20##           Resin                          161  "           "                                                                                         ##STR21##                                          162  "           "                                                                                         ##STR22##           Oil                            163  "           "                                                                                         ##STR23##           Resin                          164  "           "         3-CONH-c-C.sub.6 H.sub.11                                                                           120-122                        165  "           "         3-CONH-c-C.sub.3 H.sub.5                            166  "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                                                                  Oil                            167  "           "         3-COSH                                              168  "           "         3-COSNa                                             169  "           "         3-COSCH.sub.3                                       170  "           "         3-COSC.sub.2 H.sub.5                                171  "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                                                                       70-73                          172  "           "         3-COS-nC.sub.8 H.sub.17                             173  "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      174  "           "         3-COSCH.sub.2 CHCH.sub.2                            175  "           "         3-COSCH.sub.2 CCH                                   176  "           "         3-COS-c-C.sub.6 H.sub.11                            177  "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                    178  "           "         3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          179  "           "                                                                                         ##STR24##                                          180  "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             181  2,4-Cl.sub.2                                                                               3-CH.sub.3                                                                               5-COOCH.sub.3                                       182  "           "         5-COOC.sub.2 H.sub.5 Oil                            183  "           "         5-COO-n-C.sub.3 H.sub.7                             184  "           "         5-COO-i-C.sub.3 H.sub.7                             185  "           "         5-COO-n-C.sub.4 H.sub.9                             186  "           "         5-COO-n-C.sub.5 H.sub.11                            187  "           "         5-COO-n-C.sub.6 H.sub.13                            188  "           "         5-COO-n-C.sub.8 H.sub.17                            189  "           "         5-COO-n-C.sub.10 H.sub.21                           190  "           "                                                                                         ##STR25##                                          191  "           "         5-COOH               195-205                        192  "           "         5-COOLi                                             193  "           "         5-COONa                                             194  "           "         5-COOK                                              195  "           "         5-COOCa.sub.1 /.sub.2                               196  "           "         5-COO-c-C.sub.4 H.sub.7                             197  "           "         5-COO-c-C.sub.6 H.sub.11                            198  "           "         5-COOCH.sub.2 C.sub.6 H.sub.5                       199  "           "         5-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       200  "           "         5-COOCH.sub.2 CHCH.sub.2                            201  "           "         5-COOC.sub.2 H.sub.4 CHCH.sub.2                     202  "           "         5-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 203  "           "         5-COOCH.sub.2 CCH                                   204  "           "         5-COOC.sub.2 H.sub.4 CCH                            205  "           "         5-COO-n-C.sub.5 H.sub.10 CCH                        206  "           "         5-COOCH.sub.2 Si(CH.sub.3).sub.3                    207  "           "         5-COOC.sub.2 H.sub.4 OCH.sub.3                      208  "           "         5-CONH.sub.2                                        209  "           "         5-CN                                                210  "           "         5-CONHCH.sub.3                                      211  2,4-Cl.sub.2                                                                               3-CH.sub.3                                                                               5-CONHC.sub.2 H.sub.5                               212  "           "         5-CONH-n-C.sub.3 H.sub.7                                                                            Oil                            213  "           "         5-CONH-n-C.sub.4 H.sub.9                            214  "           "         5-CONH-n-C.sub.6 H.sub.13                           215  "           "         5-CONH-n-C.sub.10 H.sub.21                          216  "           "         5-CONH-i-C.sub.3 H.sub.7                            217  "           "         5-CON(CH.sub.3).sub.2                               218  "           "         5-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  219  "           "         5-CON(C.sub.2 H.sub.5).sub.2                        220  "           "                                                                                         ##STR26##                                          221  "           "                                                                                         ##STR27##                                          222  "           "                                                                                         ##STR28##                                          223  "           "                                                                                         ##STR29##                                          224  "           "         5-CONH-c-C.sub.6 H.sub.11                           225  "           "         5-CONH-c-C.sub.3 H.sub.5                            226  "           "         5-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  227  "           "         5-COSH                                              228  "           "         5-COSNa                                             229  "           "         5-COSCH.sub.3                                       230  "           "         5-COSC.sub.2 H.sub.5                                231  "           "         5-COSCH.sub.2 C.sub.6 H.sub.5                       232  "           "         5-COS-nC.sub.8 H.sub.17                             233  "           "         5-COSC.sub.2 H.sub.4 OCH.sub.3                      234  "           "         5-COSCH.sub.2 CHCH.sub.2                            235  "           "         5-COSCH.sub.2 CCH                                   236  "           "         5-COS-c-C.sub.6 H.sub.11                            237  "           "         5-COSCH.sub.2 Si(CH.sub.3).sub.3                    238  "           "         5-COS-n-C.sub.4 H.sub.6 CH(CH.sub.3).sub.2          239  "           "                                                                                         ##STR30##                                          240  "           "         5-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             241  2,4-Cl.sub.2                                                                               5-C.sub.2 H.sub.5                                                                        3-COOCH.sub.3                                       242  "           "         3-COOC.sub.2 H.sub.5 48-49                          243  "           "         3-COO-n-C.sub.3 H.sub.7                             244  "           "         3-COO-i-C.sub.3 H.sub.7                             245  "           "         3-COO-n-C.sub.4 H.sub.9                             246  "           "         3-COO-n-C.sub.5 H.sub.11                            247  "           "         3-COO-n-C.sub.6 H.sub.13                            248  "           "         3-COO-n-C.sub.8 H.sub.17                            249  "           "         3-COO-n-C.sub.10 H.sub.21                           250  "           "                                                                                         ##STR31##                                          251  "           "         3-COOH               193-195                        252  "           "         3-COOLi                                             253  "           "         3-COONa                                             254  "           "         3-COOK                                              255  "           "         3-COOCa.sub.1 /.sub.2                               256  "           "         3-COO-c-C.sub.4 H.sub.7                             257  "           "         3-COO-c-C.sub.6 H.sub.11                            258  "           "         3-COOCH.sub.2 C.sub.6 H.sub.5                       259  "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       260  "           "         3-COOCH.sub.2 CHCH.sub.2                            261  "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     262  "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 263  "           "         3-COOCH.sub.2 CCH                                   264  "           "         3-COOC.sub.2 H.sub.4 CCH                            265  "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        266  "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                    267  "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                      268  "           "         3-CONH.sub.2                                        269  "           "         3-CN                                                270  "           "         3-CONHCH.sub.3                                      271  2,4-Cl.sub.2                                                                               5-C.sub.2 H.sub.5                                                                        3-CONHC.sub.2 H.sub.5                               272  "           "         3-CONH-n-C.sub.3 H.sub.7                            273  "           "         3-CONH-n-C.sub.4 H.sub.9                            274  "           "         3-CONH-n-C.sub.6 H.sub.13                           275  "           "         3-CONH-n-C.sub.10 H.sub.21                          276  "           "         3-CONH-i-C.sub.3 H.sub.7                            277  "           "         3-CON(CH.sub.3).sub.2                               278  "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  279  "           "         3-CON(C.sub.2 H.sub.5).sub.2                        280  "           "                                                                                         ##STR32##                                          281  "           "                                                                                         ##STR33##                                          282  "           "                                                                                         ##STR34##                                          283  "           "                                                                                         ##STR35##                                          284  "           "         3-CONH-c-C.sub.6 H.sub.11                           285  "           "         3-CONH-c-C.sub.3 H.sub.5                            286  "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  287  "           "         3-COSH                                              288  "           "         3-COSNa                                             289  "           "         3-COSCH.sub.3                                       290  "           "         3-COSC.sub.2 H.sub.5                                291  "           "         3-COSCH.sub. 2 C.sub.6 H.sub.5                      292  "           "         3-COS-nC.sub.8 H.sub.17                             293  "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      294  "           "         3-COSCH.sub.2 CHCH.sub.2                            295  "           "         3-COSCH.sub.2 CCH                                   296  "           "         3-COS-c-C.sub.6 H.sub.11                            297  "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                    298  "           "         3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          299  "           "                                                                                         ##STR36##                                          300  "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             301  2,4-Cl.sub.2                                                                               5-CH(CH.sub.3).sub.2                                                                     3-COOCH.sub.3        144                            302  "           "         3-COOC.sub.2 H.sub.5 70-77                          303  "           "         3-COO-n-C.sub.3 H.sub.7                                                                             Ol                             304  "           "         3-COO-i-C.sub.3 H.sub.7                                                                             Ol                             305  "           "         3-COO-n-C.sub.4 H.sub.9                             306  "           "         3-COO-n-C.sub.5 H.sub.11                            307  "           "         3-COO-n-C.sub.6 H.sub.13                            308  "           "         3-COO-n-C.sub.8 H.sub.17                            309  "           "         3-COO-n-C.sub. 10 H.sub.21                          310  "           "                                                                                         ##STR37##                                          311  "           "         3-COOH               195-196                        312  "           "         3-COOLi                                             313  "           "         3-COONa              >250                           314  "           "         3-COOK                                              315  "           "         3-COOCa.sub.1 /.sub.2                               316  "           "         3-COO-c-C.sub.4 H.sub.7                             317  "           "         3-COO-c-C.sub.6 H.sub.11                            318  "           "         3-COOCH.sub.2 C.sub.6 H.sub.5                       319  "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2C.sub.6 H.sub.3)        320  "           "         3-COOCH.sub.2 CHCH.sub.2                            321  "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     322  "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 323  "           "         3-COOCH.sub.2 CCH                                   324  "           "         3-COOC.sub.2 H.sub.4 CCH                            325  "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        326  "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                    327  "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                      328  "           "         3-CONH.sub.2                                        329  "           "         3-CN                                                330  "           "         3-CONHCH.sub.3                                      331  2,4-Cl.sub.2                                                                               5-CH(CH.sub.3).sub.2                                                                     3-CONHC.sub.2 H.sub.5                                                                               106-109                        332  "           "         3-CONH-n-C.sub.3 H.sub.7                                                                            67                             333  "           "         3-CONH-n-C.sub.4 H.sub.9                            334  "           "         3-CONH-n-C.sub.6 H.sub.13                           335  "           "         3-CONH-n-C.sub.10 H.sub.21                          336  "           "         3-CONH-i-C.sub.3 H.sub.7                            337  "           "         3-CON(CH.sub.3).sub.2                               338  "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  339  "           "         3-CON(C.sub.2 H.sub.5).sub.2                                                                        98-100                         340  "           "                                                                                         ##STR38##                                          341  "           "                                                                                         ##STR39##                                          342  "           "                                                                                         ##STR40##                                          343  "           "                                                                                         ##STR41##           140-142                        344  "           "         3-CONH-c-C.sub.6 H.sub.11                           345  "           "         3-CONH-c-C.sub.3 H.sub.5                            346  "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  347  "           "         3-COSH                                              348  "           "         3-COSNa                                             349  "           "         3-COSCH.sub.3                                       350  "           "         3-COSC.sub.2 H.sub.5                                351  "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                       352  "           "         3-COS-nC.sub.8 H.sub.17                             353  "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      354  "           "         3-COSCH.sub.2 CHCH.sub.2                            355  "           "         3-COSCH.sub.2 CCH                                   356  "           "         3-COS-c-C.sub.6 H.sub.11                            357  "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                    358  "           "         3-COS-n-C.sub.4 H.sub.6 CH(CH.sub.3).sub.2          359  "           "                                                                                         ##STR42##                                          360  "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             361  2,4-Cl.sub.2                                                                               5-C(CH.sub.3).sub.3                                                                      3-COOCH.sub.3        Resin                          362  "           "         3-COOC.sub.2 H.sub.5 118-121                        363  "           "         3-COO-n-C.sub.3 H.sub.7                             364  "           "         3-COO-i-C.sub.3 H.sub.7                             365  "           "         3-COO-n-C.sub.4 H.sub.9                             366  "           "         3-COO-n-C.sub.5 H.sub.11                            367  "           "         3-COO-n-C.sub.6 H.sub.13                            368  "           "         3-COO-n-C.sub.8 H.sub.17                            369  "           "         3-COO-n-C.sub.10 H.sub.21                           370  "           "                                                                                         ##STR43##                                          371  "           "         3-COOH                                              372  "           "         3-COOLi                                             373  "           "         3-COONa                                             374  "           "         3-COOK                                              375  "           "         3-COOCa.sub.1 /.sub.2                               376  "           "         3-COO-c-C.sub.4 H.sub.7                             377  "           "         3-COO-c-C.sub.6 H.sub.11                            378  "           "         3-COOCH.sub.2 C.sub.6 H.sub.5                       379  "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       380  "           "         3-COOCH.sub.2 CHCH.sub.2                            381  "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     382  "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 383  "           "         3-COOCH.sub.2 CCH                                   384  "           "         3-COOC.sub.2 H.sub.4 CCH                            385  "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        386  "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                    387  "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                      388  "           "         3-CONH.sub.2                                        389  "           "         3-CN                                                390  "           "         3-CONHCH.sub.3                                      391  2,4-Cl.sub.2                                                                               5-C(CH.sub.3).sub.3                                                                      3-CONHC.sub.2 H.sub.5                                                                               161-162                        392  "           "         3-CONH-n-C.sub.3 H.sub.7                                                                            102-103                        393  "           "         3-CONH-n-C.sub.4 H.sub.9                            394  "           "         3-CONH-n-C.sub.6 H.sub.13                           395  "           "         3-CONH-n-C.sub.10 H.sub.21                          396  "           "         3-CONH-i-C.sub.3 H.sub.7                            397  "           "         3-CON(CH.sub.3).sub.2                               398  "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  399  "           "         3-CON(C.sub.2 H.sub.5).sub.2                        400  "           "                                                                                         ##STR44##                                          401  "           "                                                                                         ##STR45##                                          402  "           "                                                                                         ##STR46##                                          403  "           "                                                                                         ##STR47##                                          404  "           "         3-CONH-c-C.sub.6 H.sub.11                           405  "           "         3-CONH-c-C.sub.3 H.sub.5                            406  "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  407  "           "         3-COSH                                              408  "           "         3-COSNa                                             409  "           "         3-COSCH.sub.3                                       410  "           "         3-COSC.sub.2 H.sub.5                                411  "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                       412  "           "         3-COS-nC.sub.8 H.sub.17                             413  "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      414  "           "         3-COSCH.sub.2 CHCH.sub.2                            415  "           "         3-COSCH.sub.2 CCH                                   416  "           "         3-COS-c-C.sub.6 H.sub.11                            417  "           "         3-COSCH.sub.2 Si(CH.sub. 3).sub.3                   418  "           "         3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          419  "           "                                                                                         ##STR48##                                          420  "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             421  2,4-Cl.sub.2                                                                               5-CH.sub.2CH(CH.sub.3).sub.2                                                             3-COOCH.sub.3                                       422  "           "         3-COOC.sub.2 H.sub.5 Oil                            423  "           "         3-COO-n-C.sub.3 H.sub.7                             424  "           "         3-COO-i-C.sub.3 H.sub.7                             425  "           "         3-COO-n-C.sub.4 H.sub.9                             426  "           "         3-COO-n-C.sub.5 H.sub.11                            427  "           "         3-COO-n-C.sub.6 H.sub.13                            428  "           "         3-COO-n-C.sub.8 H.sub.17                            429  "           "         3-COO-n-C.sub.10 H.sub.21                           430  "           "                                                                                         ##STR49##                                          431  "           "         3-COOH                                              432  "           "         3-COOLi                                             433  "           "         3-COONa                                             434  "           "         3-COOK                                              435  "           "         3-COOCa.sub.1 /.sub.2                               436  "           "         3-COO-c-C.sub.4 H.sub.7                             437  "           "         3-COO-c-C.sub.6 H.sub.11                            438  "           "         3-COOCH.sub.2 C.sub.6 H.sub.5                       439  "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       440  "           "         3-COOCH.sub.2 CHCH.sub.2                            441  "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     442  "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 443  "           "         3-COOCH.sub.2 CCH                                   444  "           "         3-COOC.sub.2 H.sub.4 CCH                            445  "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        446  "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                    447  "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                      448  "           "         3-CONH.sub.2                                        449  "           "         3-CN                                                450  "           "         3-CONHCH.sub.3                                      451  2,4-Cl.sub.2                                                                               5-CH.sub.2 CH(CH.sub.2).sub.3                                                            3-CONHC.sub.2 H.sub.5                               452  "           "         3-CONH-n-C.sub.3 H.sub.7                            453  "           "         3-CONH-n-C.sub.4 H.sub.9                            454  "           "         3-CONH-n-C.sub.6 H.sub.13                           455  "           "         3-CONH-n-C.sub.10 H.sub.21                          456  "           "         3-CONH-i-C.sub.3 H.sub.7                            457  "           "         3-CON(CH.sub.3).sub.2                               458  "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  459  "           "         3-CON(C.sub.2 H.sub.5).sub.2                        460  "           "                                                                                         ##STR50##                                          461  "           "                                                                                         ##STR51##                                          462  "           "                                                                                         ##STR52##                                          463  "           "                                                                                         ##STR53##                                          464  "           "         3-CONH-c-C.sub.6 H.sub.11                           465  "           "         3-CONH-c-C.sub.3 H.sub.5                            466  "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  467  "           "         3-COSH                                              468  "           "         3-COSNa                                             469  "           "         3-COSCH.sub.3                                       470  "           "         3-COSC.sub.2 H.sub.5                                471  "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                       472  "           "         3-COS-nC.sub.8 H.sub.17                             473  "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      474  "           "         3-COSCH.sub.2 CHCH.sub.2                            475  "           "         3-COSCH.sub.2 CCH                                   476  "           "         3-COS-c-C.sub.6 H.sub.11                            477  "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                    478  "           "         3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          479  "           "                                                                                         ##STR54##                                          480  "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             481  2,4-Cl.sub.2                                                                               5-c-C.sub.6 H.sub.11                                                                     3-COOCH.sub.3                                       482  "           "         3-COOC.sub.2 H.sub.5 106-108                        483  "           "         3-COO-n-C.sub.3 H.sub.7                             484  "           "         3-COO-i-C.sub.3 H.sub.7                             485  "           "         3-COO-n-C.sub.4 H.sub.9                             486  "           "         3-COO-n-C.sub.5 H.sub.11                            487  "           "         3-COO-n-C.sub.6 H.sub.13                            488  "           "         3-COO-n-C.sub.8 H.sub.17                            489  "           "         3-COO-n-C.sub.10 H.sub.21                           490  "           "                                                                                         ##STR55##                                          491  "           "         3-COOH               201-202                        492  "           "         3-COOLi                                             493  "           "         3-COONa                                             494  "           "         3-COOK                                              495  "           "         3-COOCa.sub.1 /.sub.2                               496  "           "         3-COO-c-C.sub.4 H.sub.7                             497  "           "         3-COO-c-C.sub.6 H.sub.11                            498  "           "         3-COOCH.sub.2 C.sub.6 H.sub.5                       499  "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       500  "           "         3-COOCH.sub.2 CHCH.sub.2                            501  "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     502  "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 503  "           "         3-COOCH.sub.2 CCH                                   504  "           "         3-COOC.sub.2 H.sub.4 CCH                            505  "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        506  "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                    507  "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                      508  "           "         3-CONH.sub.2                                        509  "           "         3-CN                                                510  "           "         3-CONHCH.sub.3                                      511  2,4-Cl.sub.2                                                                               5-c-C.sub.6 H.sub.11                                                                     3-CONHC.sub.2 H.sub.5                                                                               131-132                        512  "           "         3-CONH-n-C.sub.3 H.sub.7                            513  "           "         3-CONH-n-C.sub.4 H.sub.9                            514  "           "         3-CONH-n-C.sub.6 H.sub.13                           515  "           "         3-CONH-n-C.sub.10 H.sub.21                          516  "           "         3-CONH-i-C.sub.3 H.sub.7                            517  "           "         3-CON(CH.sub.3).sub.2                               518  "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  519  "           "         3-CON(C.sub.2 H.sub.5).sub.2                        520  "           "                                                                                         ##STR56##                                          521  "           "                                                                                         ##STR57##                                          522  "           "                                                                                         ##STR58##                                          523  "           "                                                                                         ##STR59##                                          524  "           "         3-CONH-c-C.sub.6 H.sub.11                           525  "           "         3-CONH-c-C.sub.3 H.sub.5                            526  "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  527  "           "         3-COSH                                              528  "           "         3-COSNa                                             529  "           "         3-COSCH.sub.3                                       530  "           "         3-COSC.sub.2 H.sub.5                                531  "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                       532  "           "         3-COS-nC.sub.8 H.sub.17                             533  "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      534  "           "         3-COSCH.sub.2 CHCH.sub.2                            535  "           "         3-COSCH.sub.2 CCH                                   536  "           "         3-COS-c-C.sub.6 H.sub.11                            537  "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                    538  "           "         3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          539  "           "                                                                                         ##STR60##                                          540  "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             541  2,4-Br.sub.2                                                                               5-CH.sub.3                                                                               3-COOCH.sub.3                                       542  "           "         3-COOC.sub.2 H.sub.5 91-100                         543  "           "         3-COO-n-C.sub.3 H.sub.7                             544  "           "         3-COO-i-C.sub.3 H.sub.7                             545  "           "         3-COO-n-C.sub.4 H.sub.9                             546  "           "         3-COO-n-C.sub.5 H.sub.11                            547  "           "         3-COO-n-C.sub.6 H.sub.13                            548  "           "         3-COO-n-C.sub.8 H.sub.17                            549  "           "         3-COO-n-C.sub.10 H.sub.21                           550  "           "                                                                                         ##STR61##                                          551  "           "         3-COOH                                              552  "           "         3-COOLi                                             553  "           "         3-COONa                                             554  "           "         3-COOK                                              555  "           "         3-COOCa.sub.1 /.sub.2                               556  "           "         3-COO-c-C.sub.4 H.sub.7                             557  "           "         3-COO-c-C.sub.6 H.sub.11                            558  "           "         3-COOCH.sub.2 C.sub.6 H.sub.5                       559  "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       560  "           "         3-COOCH.sub.2 CHCH.sub.2                            561  "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     562  "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 563  "           "         3-COOCH.sub.2 CCH                                   564  "           "         3-COOC.sub.2 H.sub.4CCH                             565  "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        566  "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                    567  "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                      568  "           "         3-CONH.sub.2                                        569  "           "         3-CN                                                570  "           "         3-CONHCH.sub.3                                      571  2,4-Br.sub.2                                                                               5-CH.sub.3                                                                               3-CONHC.sub.2 H.sub.5                               572  "           "         3-CONH-n-C.sub.3 H.sub.7                            573  "           "         3-CONH-n-C.sub.4 H.sub.9                            574  "           "         3-CONH-n-C.sub.6 H.sub.13                           575  "           "         3-CONH-n-C.sub.10 H.sub.21                          576  "           "         3-CONH-i-C.sub.3 H.sub.7                            577  "           "         3-CON(CH.sub.3).sub.2                               578  "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  579  "           "         3-CON(C.sub.2 H.sub.5).sub.2                        580  "           "                                                                                         ##STR62##                                          581  "           "                                                                                         ##STR63##                                          582  "           "                                                                                         ##STR64##                                          583  "           "                                                                                         ##STR65##                                          584  "           "         3-CONH-c-C.sub.6 H.sub.11                           585  "           "         3-CONH-c-C.sub.3 H.sub.5                            586  "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  587  "           "         3-COSH                                              588  "           "         3-COSNa                                             589  "           "         3-COSCH.sub.3                                       590  "           "         3-COSC.sub.2 H.sub.5                                591  "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                       592  "           "         3-COS-nC.sub.8 H.sub.17                             593  "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      594  "           "         3-COSCH.sub.2 CHCH.sub.2                            595  "           "         3-COSCH.sub.2 CCH                                   596  "           "         3-COS-c-C.sub.6 H.sub.11                            597  "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                    598  "           "         3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3 ).sub.2         599  "           "                                                                                         ##STR66##                                          600  "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             601  3-CF.sub.3  5-CH.sub.3                                                                               3-COOCH.sub.3                                       602  "           "         3-COOC.sub.2 H.sub.5 73-75                          603  "           "         3-COO-n-C.sub.3 H.sub.7                             604  "           "         3-COO-i-C.sub.3 H.sub.7                             605  "           "         3-COO-n-C.sub.4 H.sub.9                                                                             Ol                             606  "           "         3-COO-n-C.sub.5 H.sub.11                            607  "           "         3-COO-n-C.sub.6 H.sub.13                            608  "           "         3-COO-n-C.sub.8 H.sub.17                            609  "           "         3-COO-n-C.sub.10 H.sub.21                           610  "           "                                                                                         ##STR67##                                          611  "           "         3-COOH               190-191                        612  "           "         3-COOLi                                             613  "           "         3-COONa                                             614  "           "         3-COOK                                              615  "           "         3-COOCa.sub.1 /.sub.2                               616  "           "         3-COO-c-C.sub.4 H.sub.7                             617  "           "         3-COO-c-C.sub.6 H.sub.11                            618  "           "         3-COOCH.sub.2 C.sub.6 H.sub.5                       619  "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       620  "           "         3-COOCH.sub.2 CHCH.sub.2                            621  "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     622  "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 623  "           "         3-COOCH.sub.2 CCH                                   624  "           "         3-COOC.sub.2 H.sub.4CCH                             625  "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        626  "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                    627  "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                      628  "           "         3-CONH.sub.2                                        629  "           "         3-CN                                                630  "           "         3-CONHCH.sub.3                                      631  3-CF.sub.3  5-CH.sub.3                                                                               3-CONHC.sub.2 H.sub.5                               632  "           "         3-CONH-n-C.sub.3 H.sub.7                                                                            66-72                          633  "           "         3-CONH-n-C.sub.4 H.sub.9                            634  "           "         3-CONH-n-C.sub.6 H.sub.13                           635  "           "         3-CONH-n-C.sub.10 H.sub.21                          636  "           "         3-CONH-i-C.sub.3 H.sub.7                            637  "           "         3-CON(CH.sub.3).sub.2                               638  "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  639  "           "         3-CON(C.sub.2 H.sub.5).sub.2                        640  "           "                                                                                         ##STR68##                                          641  "           "                                                                                         ##STR69##                                          642  "           "                                                                                         ##STR70##                                          643  "           "                                                                                         ##STR71##                                          644  "           "         3-CONH-c-C.sub.6 H.sub.11                           645  "           "         3-CONH-c-C.sub.3 H.sub.5                            646  "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  647  "           "         3-COSH                                              648  "           "         3-COSNa                                             649  "           "         3-COSCH.sub.3                                       650  "           "         3-COSC.sub.2 H.sub.5                                651  "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                       652  "           "         3-COS-nC.sub. 8 H.sub.17                            653  "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      654  "           "         3-COSCH.sub.2 CHCH.sub.2                            655  "           "         3-COSCH.sub.2 CCH                                   656  "           "         3-COS-c-C.sub.6 H.sub.11                            657  "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                    658  "           "         3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          659  "           "                                                                                         ##STR72##                                          660  "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             661  2,4-ClCF.sub.3                                                                             5-CH.sub.3                                                                               3-CONHC.sub.2 H.sub.5                               662  "           "         3-CONH-n-C.sub.3 H.sub.7                                                                            109-113                        663  "           "         3-CONH-n-C.sub.4 H.sub.9                            664  "           "         3-CONH-n-C.sub.6 H.sub.13                           665  "           "         3-CONH-n-C.sub.10 H.sub.21                          666  "           "         3-COHN-i-C.sub.3 H.sub.7                            667  "           "         3-CON(CH.sub.3).sub.2                               668  "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  669  "           "         3-CON(C.sub.2 H.sub.5).sub.2                        670  "           "                                                                                         ##STR73##                                          671  "           "                                                                                         ##STR74##                                          672  "           "                                                                                         ##STR75##                                          673  "           "                                                                                         ##STR76##                                          674  "           "         3-CONH-c-C.sub.6 H.sub.11                           675  "           "         3-CONH-c-C.sub.3 H.sub.5                            676  "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  677  "           "         3-COSH                                              678  "           "         3-COSNa                                             679  "           "         3-COSCH.sub.3                                       680  "           "         3-COSC.sub.2 H.sub.5                                681  "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                       682  "           "         3-COS-nC.sub.8 H.sub.17                             683  "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      684  "           "         3-COSCH.sub.2 CHCH.sub.2                            685  "           "         3-COSCH.sub.2 CCH                                   686  "           "         3-COS-c-C.sub.6 H.sub.11                            687  "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                    688  "           "         3-COS-n-C.sub. 4 H.sub.8 CH(CH.sub.3).sub.2         689  "           "                                                                                         ##STR77##                                          690  "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             691  2,4-ClCF.sub.3                                                                             5-CH.sub.3                                                                               3-COOCH.sub.3                                       692  "           "         3-COOC.sub.2 H.sub.5                                693  "           "         3-COO-n-C.sub.3 H.sub.7                             694  "           "         3-COO-i-C.sub.3 H.sub.7                             695  "           "         3-COO-n-C.sub.4 H.sub.9                             696  "           "         3-COO-n-C.sub.5 H.sub.11                            697  "           "         3-COO-n-C.sub.6 H.sub.13                            698  "           "         3-COO-n-C.sub.8 H.sub.17                            699  "           "         3-COO-n-C.sub.10 H.sub.21                           700  "           "                                                                                         ##STR78##                                          701  "           "         3-COOH                                              702  "           "         3-COOLi                                             703  "           "         3-COONa                                             704  "           "         3-COOK                                              705  "           "         3-COOCa.sub.1 /.sub.2                               706  "           "         3-COO-c-C.sub.4 H.sub.7                             707  "           "         3-COO-c-C.sub.6 H.sub.11                            708  "           "         3-COOCH.sub.2C.sub.6 H.sub.5                        709  "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2C.sub.6 H.sub.3)        710  "           "         3-COOCH.sub.2 CHCH.sub.2                            711  "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     712  "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 713  "           "         3-COOCH.sub.2 CCH                                   714  "           "         3-COOC.sub.2 H.sub.4CCH                             715  "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        716  "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                    717  "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                      718  "           "         3-CONH.sub.2 -719    " " 3-CN                       720  "           "         3-CONHCH.sub.3                                      721  4,2-ClCF.sub.3                                                                             5-CH.sub.3                                                                               3-COOCH.sub.3                                       722  "           "         3-COOC.sub.2 H.sub.5 49-51                          723  "           "         3-COO-n-C.sub.3 H.sub.7                             724  "           "         3-COO-i-C.sub.3 H.sub.7                             725  "           "         3-COO-n-C.sub. 4 H.sub.9                            726  "           "         3-COO-n-C.sub.5 H.sub.11                            727  "           "         3-COO-n-C.sub.6 H.sub.13                            728  "           "         3-COO-n-C.sub.8 H.sub.17                            729  "           "         3-COO-n-C.sub.10 H.sub.21                           730  "           "                                                                                         ##STR79##                                          731  "           "         3-COOH                                              732  "           "         3-COOLi                                             733  "           "         3-COONa                                             734  "           "         3-COOK                                              735  "           "         3-COOCa.sub.1 /.sub.2                               736  "           "         3-COO-c-C.sub.4 H.sub.7                             737  "           "         3-COO-c-C.sub.6 H.sub.11                            738  "           "         3-COOCH.sub.2 C.sub.6 H.sub.5                       739  "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       740  "           "         3-COOCH.sub.2 CHCH.sub.2                            741  "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     742  "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub. 2                743  "           "         3-COOCH.sub.2 CCH                                   744  "           "         3-COOC.sub.2 H.sub.4 CCH                            745  "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        746  "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                    747  "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                      748  "           "         3-CONH.sub.2                                        749  "           "         3-CN                                                750  "           "         3-CONHCH.sub.3                                      751  4,2-ClCF.sub.3                                                                             5-CH.sub.3                                                                               3-CONHC.sub.2 H.sub.5                               752  "           "         3-CONH-n-C.sub.3 H.sub.7                            753  "           "         3-CONH-n-C.sub.4 H.sub.9                            754  "           "         3-CONH-n-C.sub.6 H.sub.13                           755  "           "         3-CONH-n-C.sub.10 H.sub.21                          756  "           "         3-CONH-i-C.sub.3 H.sub.7                            757  "           "         3-CON(CH.sub.3).sub.2                               758  "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  759  "           "         3-CON(C.sub.2 H.sub.5).sub.2                        760  "           "                                                                                         ##STR80##                                          761  "           "                                                                                         ##STR81##                                          762  "           "                                                                                         ##STR82##                                          763  "           "                                                                                         ##STR83##                                          764  "           "         3-CONH-c-C.sub.6 H.sub.11                           765  "           "         3-CONH-c-C.sub.3 H.sub.5                            766  "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  767  "           "         3-COSH                                              768  "           "         3-COSNa                                             769  "           "         3-COSCH.sub.3                                       770  "           "         3-COSC.sub.2 H.sub.5                                771  "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                       772  "           "         3-COS-nC.sub.8 H.sub.17                             773  "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      774  "           "         3-COSCH.sub.2 CHCH.sub.2                            775  "           "         3-COSCH.sub.2 CCH                                   776  "           "         3-COS-c-C.sub.6 H.sub.11                            777  "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                    778  "           "         3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          779  "           "                                                                                         ##STR84##                                          780  "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             781  2,6,4-Cl.sub.2 CF.sub.3                                                                    5-CH.sub.3                                                                               3-COOCH.sub.3                                       782  "           "         3-COOC.sub.2 H.sub.5 138-140                        783  "           "         3-COO-n-C.sub.3 H.sub.7                             784  "           "         3-COO-i-C.sub.3 H.sub.7                             785  "           "         3-COO-n-C.sub.4 H.sub.9                             786  "           "         3-COO-n-C.sub.5 H.sub.11                            787  "           "         3-COO-n-C.sub.6 H.sub.13                            788  "           "         3-COO-n-C.sub.8 H.sub.17                            789  "           "         3-COO-n-C.sub.10 H.sub.21                           790  "           "                                                                                         ##STR85##                                          791  "           "         3-COOH                                              792  "           "         3-COOLi                                             793  "           "         3-COONa                                             794  "           "         3-COOK                                              795  "           "         3-COOCa.sub.1 /.sub.2                               796  "           "         3-COO-c-C.sub.4 H.sub.7                             797  "           "         3-COO-c-C.sub.6 H.sub.11                            798  "           "         3-COOCH.sub.2 C.sub.6 H.sub.5                       799  "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       800  "           "         3-COOCH.sub.2 CHCH.sub.2                            801  "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     802  "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 803  "           "         3-COOCH.sub.2 CCH                                   804  "           "         3-COOC.sub.2 H.sub.4 CCH                            805  "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        806  "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                    807  "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                      808  "           "         3-CONH.sub.2                                        809  "           "         3-CN                                                810  "           "         3-CONHCH.sub.3                                      811  2,6,4-Cl.sub.2 CF.sub.3                                                                    5-CH.sub.3                                                                               3-CONHC.sub.2 H.sub.5                               812  "           "         3-CONH-n-C.sub.3 H.sub.7                            813  "           "         3-CONH-n-C.sub.4 H.sub.9                            814  "           "         3-CONH-n-C.sub.6 H.sub.13                           815  "           "         3-CONH-n-C.sub.10 H.sub.21                          816  "           "         3-CONH-i-C.sub.3 H.sub.7                            817  "           "         3-CON(CH.sub.3).sub.2                               818  "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  819  "           "         3-CON(C.sub.2 H.sub.5).sub.2                        820  "           "                                                                                         ##STR86##                                          821  "           "                                                                                         ##STR87##                                          822  "           "                                                                                         ##STR88##                                          823  "           "                                                                                         ##STR89##                                          824  "           "         3-CONH-c-C.sub.6 H.sub.11                           825  "           "         3-CONH-c-C.sub.3 H.sub.5                            826  "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  827  "           "         3-COSH                                              828  "           "         3-COSNa                                             829  "           "         3-COSCH.sub.3                                       830  "           "         3-COSC.sub.2 H.sub.5                                831  "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                       832  "           "         3-COS-nC.sub.8 H.sub.17                             833  "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      834  "           "         3-COSCH.sub.2 CHCH.sub.2                            835  "           "         3-COSCH.sub.2 CCH                                   836  "           "         3-COS-c-C.sub.6 H.sub.11                            837  "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                    838  "           "         3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          839  "           "                                                                                         ##STR90##                                          840  "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             841  3,5-ClCF.sub.3                                                                             5-CH.sub.3                                                                               3-COOCH.sub.3                                       842  "           "         3-COOC.sub.2 H.sub.5 55-58                          843  "           "         3-COO-n-C.sub.3 H.sub.7                             844  "           "         3-COO-i-C.sub.3 H.sub.7                             845  "           "         3-COO-n-C.sub.4 H.sub.9                             846  "           "         3-COO-n-C.sub.5 H.sub.11                            847  "           "         3-COO-n-C.sub.6 H.sub.13                            848  "           "         3-COO-n-C.sub.8 H.sub.17                            849  "           "         3-COO-n-C.sub.10 H.sub.21                           850  "           "                                                                                         ##STR91##                                          851  "           "         3-COOH                                              852  "           "         3-COOLi                                             853  "           "         3-COONa                                             854  "           "         3-COOK                                              855  "           "         3-COOCa.sub.1 /.sub.2                               856  "           "         3-COO-c-C.sub.4 H.sub.7                             857  "           "         3-COO-c-C.sub.6 H.sub.11                            858  "           "         3-COOCH.sub.2 C.sub.6 H.sub.5                       859  "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       860  "           "         3-COOCH.sub.2 CHCH.sub.2                            861  "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     862  "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 863  "           "         3-COOCH.sub.2 CCH                                   864  "           "         3-COOC.sub.2 H.sub.4 CCH                            865  "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        866  "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                    867  "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                      868  "           "         3-CONH.sub.2                                        869  "           "         3-CN                                                870  "           "         3-CONHCH.sub.3                                      871  3,5-ClCF.sub.3                                                                             5-CH.sub.3                                                                               3-CONHC.sub.2 H.sub.5                               872  "           "         3-CONH-n-C.sub.3 H.sub.7                            873  "           "         3-CONH-n-C.sub.4 H.sub.9                            874  "           "         3-CONH-n-C.sub.6 H.sub.13                           875  "           "         3-CONH-n-C.sub.10 H.sub.21                          876  "           "         3-CONH-i-C.sub.3 H.sub.7                            877  "           "         3-CON(CH.sub.3).sub.2                               878  "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  879  "           "         3-CON(C.sub.2 H.sub.5).sub.2                        880  "           "                                                                                         ##STR92##                                          881  "           "                                                                                         ##STR93##                                          882  "           "                                                                                         ##STR94##                                          883  "           "                                                                                         ##STR95##                                          884  "           "         3-CONH-c-C.sub.6 H.sub.11                           885  "           "         3-CONH-c-C.sub.3 H.sub.5                            886  "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  887  "           "         3-COSH                                              888  "           "         3-COSNa                                             889  "           "         3-COSCH.sub.3                                       890  "           "         3-COSC.sub.2 H.sub.5                                891  "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                       892  "           "         3-COS-nC.sub.8 H.sub.17                             893  "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      894  "           "         3-COSCH.sub.2 CHCH.sub.2                            895  "           "         3-COSCH.sub.2 CCH                                   896  "           "         3-COS-c-C.sub.6 H.sub.11                            897  "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                    898  "           "         3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          899  "           "                                                                                         ##STR96##                                          900  "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             901  3,5-ClCF.sub.3                                                                             3-CH.sub.3                                                                               5-COOCH.sub.3                                       902  "           "         5-COOC.sub.2 H.sub.5 Oil                            903  "           "         5-COO-n-C.sub.3 H.sub.7                             904  "           "         5-COO-i-C.sub.3 H.sub.7                             905  "           "         5-COO-n-C.sub.4 H.sub.9                             906  "           "         5-COO-n-C.sub.5 H.sub.11                            907  "           "         5-COO-n-C.sub.6 H.sub.13                            908  "           "         5-COO-n-C.sub.8 H.sub.17                            909  "           "         5-COO-n-C.sub.10 H.sub.21                           910  "           "                                                                                         ##STR97##                                          911  "           "         5-COOH                                              912  "           "         5-COOLi                                             913  "           "         5-COONa                                             914  "           "         5-COOK                                              915  "           "         5-COOCa.sub.1 /.sub.2                               916  "           "         5-COO-c-C.sub.4 H.sub.7                             917  "           "         5-COO-c-C.sub.6 H.sub.11                            918  "           "         5-COOCH.sub.2 C.sub.6 H.sub.5                       919  "           "         5-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       920  "           "         5-COOCH.sub.2 CHCH.sub.2                            921  "           "         5-COOC.sub.2 H.sub.4 CHCH.sub.2                     922  "           "         5-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 923  "           "         5-COOCH.sub.2 CCH                                   924  "           "         5-COOC.sub.2 H.sub.4 CCH                            925  "           "         5-COO-n-C.sub.5 H.sub.10 CCH                        926  "           "         5-COOCH.sub.2 Si(CH.sub.3).sub.3                    927  "           "         5-COOC.sub.2 H.sub.4 OCH.sub.3                      928  "           "         5-CONH.sub.2                                        929  "           "         5-CN                                                930  "           "         5-CONHCH.sub.3                                      931  3,5-ClCF.sub.3                                                                             3-CH.sub.3                                                                               5-CONHC.sub.2 H.sub.5                               932  "           "         5-CONH-n-C.sub.3 H.sub.7                            933  "           "         5-CONH-n-C.sub.4 H.sub.9                            934  "           "         5-CONH-n-C.sub.6 H.sub.13                           935  "           "         5-CONH-n-C.sub.10 H.sub.21                          936  "           "         5-CONH-i-C.sub.3 H.sub.7                            937  "           "         5-CON(CH.sub.3).sub.2                               938  "           "         5-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  939  "           "         5-CON(C.sub.2 H.sub.5).sub.2                        940  "           "                                                                                         ##STR98##                                          941  "           "                                                                                         ##STR99##                                          942  "           "                                                                                         ##STR100##                                         943  "           "                                                                                         ##STR101##                                         944  "           "         5-CONH-c-C.sub.6 H.sub.11                           945  "           "         5-CONH-c-C.sub.3 H.sub.5                            946  "           "         5-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  947  "           "         5-COSH                                              948  "           "         5-COSNa                                             949  "           "         5-COSCH.sub.3                                       950  "           "         5-COSC.sub.2 H.sub.5                                951  "           "         5-COSCH.sub.2 C.sub.6 H.sub.5                       952  "           "         5-COS-nC.sub.8 H.sub.17                             953  "           "         5-COSC.sub.2 H.sub.4 OCH.sub.3                      954  "           "         5-COSCH.sub.2 CHCH.sub.2                            955  "           "         5-COSCH.sub.2 CCH                                   956  "           "         5-COS-c-C.sub.6 H.sub.11                            957  "           "         5-COSCH.sub.2 Si(CH.sub.3).sub.3                    958  "           "         5-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          959  "           "                                                                                         ##STR102##                                         960  "           "         5-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             961  2,3-Cl.sub.2                                                                               5-CH.sub.3                                                                               3-COOCH.sub.3                                       962  "           "         3-COOC.sub.2 H.sub.5 77-79                          963  "           "         3-COO-n-C.sub.3 H.sub.7                             964  "           "         3-COO-i-C.sub.3 H.sub.7                             965  "           "         3-COO-n-C.sub.4 H.sub.9                             966  "           "         3-COO-n-C.sub.5 H.sub.11                            967  "           "         3-COO-n-C.sub.6 H.sub.13                            968  "           "         3-COO-n-C.sub.8 H.sub.17                            969  "           "         3-COO-n-C.sub.10 H.sub.21                           970  "           "                                                                                         ##STR103##                                         971  "           "         3-COOH                                              972  "           "         3-COOLi                                             973  "           "         3-COONa                                             974  "           "         3-COOK                                              975  "           "         3-COOCa.sub.1 /.sub.2                               976  "           "         3-COO-c-C.sub.4 H.sub.7                             977  "           "         3-COO-c-C.sub.6 H.sub.11                            978  "           "         3-COOCH.sub.2 C.sub.6 H.sub.5                       979  "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2  C.sub.6 H.sub.3)      980  "           "         3-COOCH.sub.2 CHCH.sub.2                            981  "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     982  "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 983  "           "         3-COOCH.sub.2 CCH                                   984  "           "         3-COOC.sub.2 H.sub.4CCH                             985  "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        986  "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                    987  "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                      988  "           "         3-CONH.sub.2                                        989  "           "         3-CN                                                990  "           "         3-CONHCH.sub.3                                      991  2,3-Cl.sub.2                                                                               5-CH.sub.3                                                                               3-CONHC.sub.2 H.sub.5                               992  "           "         3-CONH-n-C.sub.3 H.sub.7                            993  "           "         3-CONH-n-C.sub.4 H.sub.9                            994  "           "         3-CONH-n-C.sub.6 H.sub.13                           995  "           "         3-CONH-n-C.sub.10 H.sub.21                          996  "           "         3-CONH-i-C.sub.3 H.sub.7                            997  "           "         3-CON(CH.sub.3).sub.2                               998  "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  999  "           "         3-CON(C.sub.2 H.sub.5).sub.2                        1000 "           "                                                                                         ##STR104##                                         1001 "           "                                                                                         ##STR105##                                         1002 "           "                                                                                         ##STR106##                                         1003 "           "                                                                                         ##STR107##                                         1004 "           "         3-CONH-c-C.sub.6 H.sub.11                           1005 "           "         3-CONH-c-C.sub.3 H.sub.5                            1006 "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  1007 "           "         3-COSH                                              1008 "           "         3-COSNa                                             1009 "           "         3-COSCH.sub.3                                       1010 "           "         3-COSC.sub.2 H.sub.5                                1011 "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                       1012 "           "         3-COS-nC.sub.8 H.sub.17                             1013 "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      1014 "           "         3-COSCH.sub.2 CHCH.sub.2                            1015 "           "         3-COSCH.sub.2 CCH                                   1016 "           "         3-COS-c-C.sub.6 H.sub.11                            1017 "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                    1018 "           "         3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          1019 "           "                                                                                         ##STR108##                                         1020 "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             1021 2,4,5-Cl.sub.2 OCH.sub.3                                                                   5-CH.sub.3                                                                               3-COOCH.sub.3                                       1022 "           "         3-COOC.sub.2 H.sub.5 155-159                        1023 "           "         3-COO-n-C.sub.3 H.sub.7                             1024 "           "         3-COO-i-C.sub.3 H.sub.7                             1025 "           "         3-COO-n-C.sub.4 H.sub.9                             1026 "           "         3-COO-n-C.sub.5 H.sub.11                            1027 "           "         3-COO-n-C.sub.6 H.sub.13                            1028 "           "         3-COO-n-C.sub.8 H.sub.17                            1029 "           "         3-COO-n-C.sub.10 H.sub.21                           1030 "           "                                                                                         ##STR109##                                         1031 "           "         3-COOH                                              1032 "           "         3-COOLi                                             1033 "           "         3-COONa                                             1034 "           "         3-COOK                                              1035 "           "         3-COOCa.sub.1 /.sub.2                               1036 "           "         3-COO-c-C.sub.4 H.sub.7                             1037 "           "         3-COO-c-C.sub.6 H.sub.11                            1038 "           "         3-COOCH.sub.2 C.sub.6 H.sub.5                       1039 "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       1040 "           "         3-COOCH.sub.2 CHCH.sub.2                            1041 "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     1042 "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 1043 "           "         3-COOCH.sub.2 CCH                                   1044 "           "         3-COOC.sub.2 H.sub.4 CCH                            1045 "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        1046 "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                    1047 "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                      1048 "           "         3-CONH.sub.2                                        1049 "           "         3-CN                                                1050 "           "         3-CONHCH.sub.3                                      1051 2,4,5-Cl.sub.2 OCH.sub.3                                                                   5-CH.sub.3                                                                               3-CONHC.sub.2 H.sub.5                               1052 "           "         3-CONH-n-C.sub.3 H.sub.7                            1053 "           "         3-CONH-n-C.sub.4 H.sub.9                            1054 "           "         3-CONH-n-C.sub.6 H.sub.13                           1055 "           "         3-CONH-n-C.sub.10 H.sub.21                          1056 "           "         3-CONH-i-C.sub.3 H.sub.7                            1057 "           "         3-CON(CH.sub.3).sub.2                               1058 "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  1059 "           "         3-CON(C.sub.2 H.sub.5).sub.2                        1060 "           "                                                                                         ##STR110##                                         1061 "           "                                                                                         ##STR111##                                         1062 "           "                                                                                         ##STR112##                                         1063 "           "                                                                                         ##STR113##                                         1064 "           "         3-CO NH-c-C.sub.6 H.sub.11                          1065 "           "         3-CONH-c-C.sub.3 H.sub.5                            1066 "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  1067 "           "         3-COSH                                              1068 "           "         3-COSNa                                             1069 "           "         3-COSCH.sub.3                                       1070 "           "         3-COSC.sub.2 H.sub.5                                1071 "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                       1072 "           "         3-COS-nC.sub.8 H.sub.17                             1073 "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      1074 "           "         3-COSCH.sub.2 CHCH.sub.2                            1075 "           "         3-COSCH.sub.2 CCH                                   1076 "           "         3-COS-c-C.sub.6 H.sub.11                            1077 "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                    1078 "           "         3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          1079 "           "                                                                                         ##STR114##                                         1080 "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             1081 2,4,5-Cl.sub.2 OCH.sub.3                                                                   3-CH.sub.3                                                                               5-COOCH.sub. 3                                      1082 "           "         5-COOC.sub.2 H.sub.5 Oil                            1083 "           "         5-COO-n-C.sub.3 H.sub.7                             1084 "           "         5-COO-i-C.sub.3 H.sub.7                             1085 "           "         5-COO-n-C.sub.4 H.sub.9                             1086 "           "         5-COO-n-C.sub.5 H.sub.11                            1087 "           "         5-COO-n-C.sub.6 H.sub.13                            1088 "           "         5-COO-n-C.sub.8 H.sub.17                            1089 "           "         5-COO-n-C.sub.10 H.sub.21                           1090 "           "                                                                                         ##STR115##                                         1091 "           "         5-COOH                                              1092 "           "         5-COOLi                                             1093 "           "         5-COONa                                             1094 "           "         5-COOK                                              1095 "           "         5-COOCa.sub.1 /.sub.2                               1096 "           "         5-COO-c-C.sub.4 H.sub.7                             1097 "           "         5-COO-c-C.sub.6 H.sub.11                            1098 "           "         5-COOCH.sub.2 C.sub.6 H.sub.5                       1099 "           "         5-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       1100 "           "         5-COOCH.sub.2 CHCH.sub.2                            1101 "           "         5-COOC.sub.2 H.sub.4 CHCH.sub.2                     1102 "           "         5-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                 1103 "           "         5-COOCH.sub.2 CCH                                   1104 "           "         5-COOC.sub.2 H.sub.4 CCH                            1105 "           "         5-COO-n-C.sub.5 H.sub.10 CCH                        1106 "           "         5-COOCH.sub.2 Si(CH.sub.3).sub.3                    1107 "           "         5-COOC.sub.2 H.sub.4 OCH.sub.3                      1108 "           "         5-CONH.sub.2                                        1109 "           "         5-CN                                                1110 "           "         5-CONHCH.sub.3                                      1111 2,4,5-Cl.sub.2 OCH.sub.3                                                                   3-CH.sub.3                                                                               5-CONHC.sub.2 H.sub.5                               1112 "           "         5-CONH-n-C.sub.3 H.sub.7                            1113 "           "         5-CONH-n-C.sub.4 H.sub.9                            1114 "           "         5-CONH-n-C.sub.6 H.sub.13                           1115 "           "         5-CONH-n-C.sub.10 H.sub.21                          1116 "           "         5-CONH-i-C.sub.3 H.sub.7                            1117 "           "         5-CON(CH.sub.3).sub.2                               1118 "           "         5-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  1119 "           "         5-CON(C.sub.2 H.sub.5).sub.2                        1120 "           "                                                                                         ##STR116##                                         1121 "           "                                                                                         ##STR117##                                         1122 "           "                                                                                         ##STR118##                                         1123 "           "                                                                                         ##STR119##                                         1124 "           "         5-CONH-c-C.sub.6 H.sub.11                           1125 "           "         5-CONH-c-C.sub.3 H.sub.5                            1126 "           "         5-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  1127 "           "         5-COSH                                              1128 "           "         5-COSNa                                             1129 "           "         5-COSCH.sub.3                                       1130 "           "         5-COSC.sub.2 H.sub.5                                1131 "           "         5-COSCH.sub.2 C.sub.6 H.sub.5                       1132 "           "         5-COS-nC.sub. 8 H.sub.17                            1133 "           "         5-COSC.sub.2 H.sub.4 OCH.sub.3                      1134 "           "         5-COSCH.sub.2 CHCH.sub.2                            1135 "           "         5-COSCH.sub.2 CCH                                   1136 "           "         5-COS-c-C.sub.6 H.sub.11                            1137 "           "         5-COSCH.sub.2 Si(CH.sub.3).sub.3                    1138 "           "         5-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          1139 "           "                                                                                         ##STR120##                                         1140 "           "         5-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             1141 2,6,3-(C.sub.2 H.sub.5).sub.2 Cl                                                           5-CH.sub.3                                                                               3-COOCH.sub.3                                       1142 "           "         3-COOC.sub.2 H.sub.5 Oil                            1143 "           "         3-COO-n-C.sub.3 H.sub.7                             1144 "           "         3-COO-i-C.sub.3 H.sub.7                             1145 "           "         3-COO-n-C.sub.4 H.sub.9                             1146 "           "         3-COO-n-C.sub.5 H.sub.11                            1147 "           "         3-COO-n-C.sub.6 H.sub.13                            1148 "           "         3-COO-n-C.sub.8 H.sub.17                            1149 "           "         3-COO-n-C.sub.10 H.sub.21                           1150 "           "                                                                                         ##STR121##                                         1151 "           "         3-COOH                                              1152 "           "         3-COOLi                                             1153 "           "         3-COONa                                             1154 "           "         3-COOK                                              1155 "           "         3-COOCa.sub.1 /.sub.2                               1156 "           "         3-COO-c-C.sub.4 H.sub.7                             1157 "           "         3-COO-c-C.sub.6 H.sub.11                            1158 "           "         3-COOCH.sub.2 C.sub.6 H.sub.5                       1159 "           "         3-COOCH.sub.2 -(2,4-Cl.sub.2 C.sub.6 H.sub.3)       1160 "           "         3-COOCH.sub.2 CHCH.sub.2                            1161 "           "         3-COOC.sub.2 H.sub.4 CHCH.sub.2                     1162 "           "         3-COO-n-C.sub.8 H.sub.16 CHCH.sub.3                 1163 "           "         3-COOCH.sub.2 CCH                                   1164 "           "         3-COOC.sub.2 H.sub. 4 CCH                           1165 "           "         3-COO-n-C.sub.5 H.sub.10 CCH                        1166 "           "         3-COOCH.sub.2 Si(CH.sub.3).sub.3                    1167 "           "         3-COOC.sub.2 H.sub.4 OCH.sub.3                      1168 "           "         3-CONH.sub.2                                        1169 "           "         3-CN                                                1170 "           "         3-CONHCH.sub.3                                      1171 2,6,3-(C.sub.2 H.sub.5).sub.2 Cl                                                           5-CH.sub.3                                                                               3-CONHC.sub.2 H.sub.5                               1172 "           "         3-CONH-n-C.sub.3 H.sub.7                            1173 "           "         3-CONH-n-C.sub.4 H.sub.9                            1174 "           "         3-CONH-n-C.sub.6 H.sub.13                           1175 "           "         3-CONH-n-C.sub.10 H.sub.21                          1176 "           "         3-CONH-i-C.sub.3 H.sub.7                            1177 "           "         3-CON(CH.sub.3).sub.2                               1178 "           "         3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                  1179 "           "         3-CON(C.sub.2 H.sub.5).sub.2                        1180 "           "                                                                                         ##STR122##                                         1181 "           "                                                                                         ##STR123##                                         1182 "           "                                                                                         ##STR124##                                         1183 "           "                                                                                         ##STR125##                                         1184 "           "         3-CONH-c-C.sub.6 H.sub.11                           1185 "           "         3-CONH-c-C.sub.3 H.sub.5                            1186 "           "         3-CON(CH.sub.3)(cC.sub.6 H.sub.11)                  1187 "           "         3-COSH                                              1188 "           "         3-COSNa                                             1189 "           "         3-COSCH.sub.3                                       1190 "           "         3-COSC.sub.2 H.sub.5                                1191 "           "         3-COSCH.sub.2 C.sub.6 H.sub.5                       1192 "           "         3-COS-nC.sub.8 H.sub.17                             1193 "           "         3-COSC.sub.2 H.sub.4 OCH.sub.3                      1194 "           "         3-COSCH.sub.2 CHCH.sub.2                            1195 "           "         3-COSCH.sub.2 CCH                                   1196 "           "         3-COS-c-C.sub.6 H.sub.11                            1197 "           "         3-COSCH.sub.2 Si(CH.sub.3).sub.3                    1198 "           "         3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2          1199 "           "                                                                                         ##STR126##                                         1200 "           "         3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2             1201 3-CF.sub.3  3-CH.sub.3                                                                               5-COOH               164-170                        1202 3,2,6-Cl(C.sub.2 H.sub.5).sub.2                                                            "         5-COOC.sub.2 H.sub.5 Oil                            1203 4,2-ClCF.sub.3 Phe                                                                         3-CH.sub.6                                                                               5-COOC.sub.2 H.sub.5 Oil                            1204 3-CF.sub.3  5-C(CH.sub.3).sub.3                                                                      3-COOC.sub.2 H.sub.5 Oil                            1205 2,4-Br.sub.2                                                                               5-C(CH.sub.3).sub.3                                                                      3-COOC.sub.2 H.sub.5 130-132                        1206 2,3-Cl.sub.2                                                                               5-C(CH.sub.3).sub.3                                                                      3-COOC.sub.2 H.sub.5 101-102                        1207 2,6,4-Cl.sub.2 CF.sub.3                                                                    3-CH.sub.2 CH(CH.sub.3).sub.2                                                            5-COOC.sub.2 H.sub.5 Oil                            1208 "           5-CH.sub.2 CH(CH.sub.3).sub.2                                                            3-COOC.sub.2 H.sub.5 82-84                          1209 2,4-Cl.sub.2                                                                               3-CH.sub.2 CH(CH.sub.3).sub.2                                                            5-COOC.sub.2 H.sub.5 Oil                            1210 2,4-Br.sub.2                                                                               3-i-C.sub.3 H.sub.7                                                                      5-COOC.sub.2 H.sub.5                                1211 3-CF.sub.3  5-CH.sub.2 CH(CH.sub.3).sub.2                                                            3-COOC.sub.2 H.sub.5 Oil                            1212 2,6,4-Cl.sub.2 CF.sub.3                                                                    5-CH.sub. 2 CH(CH.sub.3).sub.2                                                           3-COOH               191--193                       1213 2,3-Cl.sub.2 Phe                                                                           5-CH      3-COOC.sub.2 H.sub.5 76-78                          1214 "           5-CH.sub.2 CH(CH.sub.3)                                                                  3-COOC.sub.2 H.sub.5 91-92                          1215 2,4-Br.sub.2                                                                               5-CH.sub.2 CH(CH.sub.3)                                                                  3-COOEt              Oil                            1216 2,4-Cl.sub.2                                                                               5-CH.sub.3                                                                               3-COOCH.sub.2 CH(CH.sub.3)CH.sub.2 CH.sub.3                                                         39-45                          1217 3-CF.sub.3  5-CH.sub.3                                                                               3-COOC.sub.2 H.sub.5 Oil                            1218 2,4-Br.sub.2                                                                               5-CH(CH.sub.3).sub.2                                                                     3-COOC.sub.2 H.sub.5 72-79                          1219 2,4-ClCF.sub.3                                                                             3-CH(CH.sub.3).sub.2                                                                     5-COOC.sub.2 H.sub.5 Oil                            1220 "           5-CH(CH.sub.3).sub.2                                                                     3-COOC.sub.2 H.sub.5 58-70                          1221 2,4-Br.sub.2                                                                               5-CH.sub.2 CH(CH.sub.3).sub.2                                                            3-COOC.sub.2 H.sub.5 184-187                        1222 2,4-ClCF.sub.3                                                                             5-C(CH.sub.3).sub.3                                                                      3-COOC.sub.2 H.sub.5 106-107                        1223 2,6,4-Cl.sub.2 CF.sub.3                                                                    5-CH.sub.2 CH(CH.sub.3).sub.2                                                            3-COO.sup.- Li.sup.+ >250                           1224 2,3-Cl.sub.2                                                                               5-CH.sub.2 CH(CH.sub.3).sub.2                                                            3-COOH               209-211                        1225 2,4-ClCF.sub.3                                                                             5-CH.sub.2 CH(CH.sub.3).sub.2                                                            3-COOC.sub.2 H.sub.5 54-58                          1226 2,4,5-Cl, FCH.sub.3 Phe                                                                    5-CH.sub.3                                                                               3-COOC.sub.2 H.sub.5 109-110                        1227 3,4-Cl, CH.sub.3 Phe                                                                       5-CH.sub.3                                                                               3-COOC.sub.2 H.sub.5 77-80                          1228 2,4-Cl.sub.2 Phe                                                                           5-CH.sub.3                                                                               3-COO HN(C.sub.2 H.sub.4 OH).sub.3                                                                  135-138                        1229 2,4-Cl.sub.2 Phe                                                                           5-CH.sub.3                                                                               3-CONHC(CH.sub.3)(CH(CH.sub.3).sub.2)CONH.sub.2                                2                    65-69                          1230 2,4-Cl.sub.2 Phe                                                                           5-CH.sub.3                                                                               3-C(NH.sub.2)NOH     205                            1231 2,6-(CH.sub.3).sub.2                                                                       5-CH.sub.3                                                                               3-COOC.sub.2 H.sub.5 Oil                            1232 4-FPhe      5-CH.sub.3                                                                               3-COOC.sub.2 H.sub.5 Resin                          1233 4-OCH.sub.3 Phe                                                                            5-CH.sub.3                                                                               3-COOC.sub.2 H.sub.5 Oil                            1234 2,4-Cl, CF.sub.3 Phe                                                                       3-CH.sub.3                                                                               5-COOC.sub.2 H.sub.5 Oil                            1235 2,4-Cl.sub.2                                                                               5-c-C.sub.3 H.sub.5                                                                      3-COOC.sub.2 H.sub.5 80                             1236 2,6,4-Cl.sub.2, CF.sub.3 Phe                                                               5-c-C.sub.3 H.sub.5                                                                      3-COOC.sub.2 H.sub.5 105-110                        __________________________________________________________________________      Abbreviations:                                                                 n: straightchain                                                               i: iso (branched)                                                              c: cyclo                                                                 

C. Biological Examples Example 1

Wheat and barley were grown to the 3- to 4-leaf stage in plastic pots in a greenhouse and were then treated in succession by the post-emergence method with the safener compounds and the herbicides tested. The herbicides and the compounds of the formula I were applied here in the form of aqueous suspensions or emulsions with a water application amount, when converted, of 800 l/ha. 3 to 4 weeks after the treatment, the plants were rated visually for any type of damage by the herbicides applied, the extent of the persistent inhibition of growth being taken into particular account. The degree of damage or the safener action of I was determined in % damage.

The results from Table I illustrate that the compounds according to the invention can effectively reduce severe herbicide damage to the crop plants.

Even in cases of high overdoses of the herbicide, severe damage occurring to the crop plants is significantly reduced, and milder damage is eliminated completely. Mixtures of herbicides and compounds according to the invention are therefore advantageously suitable for selectively combating weeds in cereal crops.

                  TABLE 1                                                          ______________________________________                                         Safener action of the compounds according to the invention                                                % damage                                            Combination  Dosage        (safener action)                                    Herbicide/Safener                                                                           (kg of a.s./ha)                                                                              TA      HV                                          ______________________________________                                         H1           2.0           80      --                                                       0.2           --      85                                          H1 + 122     2.0 + 2.5     10      --                                                       0.2 + 2.5     --      20                                          H1 + 148     2.0 + 2.5     50      --                                                       0.2 + 2.5     --      40                                          H1 + 182     2.0 + 2.5     40      --                                                       0.2 + 2.5     --      35                                          H1 + 542     2.0 + 2.5     30      --                                                       0.2 + 2.5     --      35                                          H1 + 131     2.0 + 2.5     20      --                                                       0.2 + 2.5     --      40                                          H1 + 191     2.0 + 2.5     20      --                                                       0.2 + 2.5     --      45                                          H1 + 1       2.0 + 2.5     15      --                                                       0.2 + 2.5     --      45                                          H1 + 782     2.0 + 2.5     20      --                                                       0.2 +  2.5    --      40                                          H1 + 602     2.0 + 2.5     20      --                                                       0.2 + 2.5     --      50                                          H1 + 1201    2.0 + 2.5     35      --                                                       0.2 + 2.5     --      50                                          H1 + 611     2.0 + 2.5     35      --                                                       0.2 + 2.5     --      50                                          H1 + 1202    2.0 + 2.5     50      --                                                       0.2 + 2.5     --      70                                          H1 + 1142    2.0 + 2.5     25      --                                                       0.2 + 2.5     --      40                                          H1 + 842     2.0 + 2.5     25      --                                                       0.2 + 2.5     --      30                                          H1 + 902     2.0 + 2.5     50      --                                                       0.2 + 2.5     --      55                                          H1 + 71      2.0 + 2.5     50      --                                                       0.2 + 2.5     --      65                                          H1 + 632     2.0 + 2.5     30      --                                                       0.2 + 2.5     --      85                                          H1 + 605     2.0 + 2.5     70      --                                                       0.2 + 2.5     --      40                                          H1 + 722     2.0 + 2.5     20      --                                                       0.2 + 2.5     --      50                                          H1 + 152     2.0 + 2.5     40      --                                                       0.2 + 2.5     --      85                                          H1 + 212     2.0 + 2.5     40      --                                                       0.2 + 2.5     --      70                                          H1 + 302     2.0 + 2.5     60      --                                                       0.2 + 2.5     --      30                                          H1 + 362     2.0 + 2.5     20      --                                                       0.2 + 2.5     --      20                                          H1 + 1204    2.0 + 2.5     60      --                                                       0.2 + 2.5     --      50                                          H1 + 1205    2.0 + 2.5     60      --                                                       0.2 + 2.5     --      50                                          H1 + 1206    2.0 + 2.5     60      --                                                       0.2 + 2.5     --      50                                          H1 + 1207    2.0 + 2.5     55      --                                                       0.2 + 2.5     --      45                                          H1 + 1208    2.0 + 2.5     60      --                                                       0.2 + 2.5     --      45                                          H1 + 1209    2.0 + 2.5     70      --                                                       0.2 +  2.5    --      45                                          H1 + 422     2.0 + 2.5     70      --                                                       0.2 + 2.5     --      50                                          H1 + 1210    2.0 + 2.5     70      --                                                       0.2 + 2.5     --      55                                          H1 + 1211    2.0 + 2.5     60      --                                                       0.2 + 2.5     --      50                                          H1 + 1212    2.0 + 2.5     70      --                                                       0.2 + 2.5     --      40                                          H1 + 1213    2.0 + 2.5     40      --                                                       0.2 + 2.5     --      30                                          H1 + 1214    2.0 + 2.5     60      --                                                       0.2 + 2.5     --      10                                          H.sub.1 + 121                                                                               2,0 + 2,5     25      --                                                       0,2 + 2,5     --      40                                          H.sub.1 + 123                                                                               "             60      --                                                       "             --      40                                          H.sub.1 + 124                                                                                2,0 + 1,25   20      --                                                        0,2 + 1,25   --      30                                          H.sub.1 + 125                                                                               2,0 + 2,5     60      --                                                       0,2 + 2,5     --      40                                          H.sub.1 + 127                                                                               "             40      --                                                       "             --      30                                          H.sub.1 + 128                                                                                2,0 + 1,25   20      --                                                        0,2 + 1,25   --      40                                          H.sub.1 + 132                                                                               2,0 + 2,5     30      --                                                       0,2 + 2,5     --      30                                          H.sub.1 + 133                                                                                2,0 + 1,25   20      --                                                        0,2 + 1,25   --      30                                          H.sub.1 + 135                                                                               2,0 + 2,5     30      --                                                       0,2 + 2,5     --      30                                          H.sub.1 + 137                                                                                2,0 + 1,25   40      --                                                        0,2 + 1,25   --      50                                          H.sub.1 + 138                                                                               "             10      --                                                       "             --      20                                          H.sub.1 + 140                                                                               "             20      --                                                       "             --      40                                          H.sub.1 + 143                                                                               "             15      --                                                       "             --      60                                          H.sub.1 + 146                                                                                2,0 + 1,25   40      --                                                        0,2 + 1,25   --      70                                          H.sub.1 + 147                                                                               "             20      --                                                       "             --      20                                          H.sub.1 + 149                                                                               "             35      --                                                       "             --      40                                          H.sub.1 + 150                                                                               "             30      --                                                       "             --      80                                          H.sub.1 + 153                                                                               "             10      --                                                       "             --      30                                          H.sub.1 + 157                                                                               "             50      --                                                       "             --      75                                          H.sub.1 + 159                                                                               "             20      --                                                       "             --      20                                          H.sub.1 + 160                                                                               "             50      --                                                       "             --      60                                          H.sub.1 + 162                                                                               "             30      --                                                       "             --      80                                          H.sub.1 + 164                                                                               "             10      --                                                       "             --      70                                          H.sub.1 + 171                                                                               "             20      --                                                       "             --      75                                          H.sub.1 + 242                                                                               "             20      --                                                       "             --      30                                          H.sub.1 + 251                                                                               "             20      --                                                       "             --      20                                          H.sub.1 + 301                                                                               "             20      --                                                       "             --      30                                          H.sub.1 + 303                                                                               "             10      --                                                       "             --      20                                          H.sub.1 + 311                                                                               "             30      --                                                       "             --      30                                          H.sub.1 + 361                                                                                2,0 + 1,25   15      --                                                        0,2 + 1,25   --      20                                          H.sub.1 + 391                                                                               "             25      --                                                       "             --      50                                          H.sub.1 + 392                                                                               "             20      --                                                       "             --      70                                          H.sub.1 + 482                                                                               "             20      --                                                       "             --      40                                          H.sub.1 + 491                                                                               "             20      --                                                       "             --      40                                          H.sub.1 + 511                                                                               "             30      --                                                       "             --      85                                          H.sub.1 + 692                                                                               "             30      --                                                       "             --      40                                          H.sub.1 + 1022                                                                              "             30      --                                                       "             --      70                                          H.sub. 1 + 1218                                                                             2,0 + 2,5     30      --                                                       0,2 + 2,5     --      20                                          H.sub.1 + 1219                                                                              "             35      --                                                       "             --      50                                          H.sub.1 + 1220                                                                              "             30      --                                                       "             --      20                                          H.sub.1 + 1221                                                                              "             30      --                                                       "             --      20                                          H.sub.1 + 1222                                                                              "             15      --                                                       "             --      30                                          H.sub.1 + 1223                                                                              "             20      --                                                       "             --      60                                          H.sub.1 + 1224                                                                              "             20      --                                                       "             --      60                                          H.sub.1 + 1225                                                                              "             50      --                                                       "             --      30                                          H.sub.1 + 1226                                                                               2,0 + 1,25   30      --                                                        0,2 + 1,25   --      70                                          H.sub.1 + 1227                                                                              "             50      --                                                       "             --      80                                          H.sub.1 + 1228                                                                              "             40      --                                                       "             --      70                                          H.sub.1 +  1229                                                                             "             30                                                               "             --      60                                          H.sub.1 + 1230                                                                              "             50      --                                                       "             --      80                                          H.sub.1 + 1231                                                                              "             40      --                                                       "             --      75                                          H.sub.1 + 1233                                                                              "             40      --                                                       "             --      75                                          H.sub.1 + 1235                                                                              "             20      --                                                       "             --      40                                          H.sub.1 + 1236                                                                              "             20      --                                                       "             --      60                                          ______________________________________                                          Abbreviations:                                                                 TA = Triticum aestivum (wheat)                                                 HV = Hordeum vulgare (barley)                                                  a.s. = active substance                                                        H1 = fenoxapropethyl                                                      

We claim:
 1. An agent for protecting crop plants from the phytotoxic side effects of the herbicide ethyl 2-(4-(6-chlorobenzoxazol-2-yloxy)-phenoxy)-propionate, which agent comprises an amount effective for protecting crop plants from phytotoxic side effects of the herbicide, of the safener compound ethyl 1-(2,4-dichlorophenyl)-5-isopropyl-pyrazole-3-carboxylate in combination with the herbicide, in a weight ratio of safener to herbicide ethyl 2-(4-6-chlorobenzoxazol-2-yloxy)-phenoxy)-propionate of 1:1 to 1:10.
 2. An agent for protecting crop plants from the phytotoxic side effects of the herbicide ethyl 2-(4-(6-chlorobenzoxazol-2-yloxy)-phenoxy)-propionate, which agent comprises an amount effective for protecting crop plants from phytotoxic side effects of the herbicide, of the safener compound 1-(2,4-dichlorophenyl)-5-isopropyl-pyrazole-3-carboxylic acid in combination with the herbicide, in a weight ratio of safener to herbicide ethyl 2-(4-6-chlorobenzoxazol-2-yloxy)-phenoxy)-propionate of 1:1 to 1:10.
 3. A method for protecting crop plants from phytotoxic side effects of the herbicide ethyl 2-(4-(6-chlorobenzoxazol-2-yloxy)-phenoxy)-propionate, which comprises treating the plants, seeds of the plants or their cultivation areas with an effective amount of the safener compound ethyl 1-(2,4-dichlorophenyl)-5-isopropyl-pyrazole-3-carboxylate before, after, or at the same time, as treating with the herbicide, in a weight ratio of safener to herbicide ethyl 2-(4-6-chlorobenzoxazol-2-yloxy)-phenoxy)-propionate of 1:1 to 1:10.
 4. A method for protecting crop plants from phytotoxic side effects of the herbicide ethyl 2-(4-(6-chlorobenzoxazol-2-yloxy)-phenoxy)-propionate, which comprises treating the plants, seeds of the plants or their cultivation areas with an effective amount of the safener compound 1-(2,4-dichlorophenyl)-5-isopropyl-pyrazole-3-carboxylic acid before, after, or at the same time, as treating with the herbicide, in a weight ratio of safener to herbicide ethyl 2-(4-6-chlorobenzoxazol-2-yloxy)-phenoxy)-propionate of 1:1 to 1:10. 